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dc.contributor.authorRedondo Realinho, Vera Cristina de
dc.contributor.authorAntunes, Marcelo de Sousa Pais
dc.contributor.authorVelasco Perero, José Ignacio
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament de Ciència dels Materials i Enginyeria Metal·lúrgica
dc.date.accessioned2016-07-26T11:29:58Z
dc.date.available2018-07-03T00:30:46Z
dc.date.issued2016-06
dc.identifier.citationDe Redondo, V., De Sousa Pais, M., Velasco J.I. Enhanced fire behavior of Casico-based foams. "Polymer degradation and stability", Juny 2016, vol. 128, p. 260-268.
dc.identifier.issn0141-3910
dc.identifier.urihttp://hdl.handle.net/2117/89223
dc.description.abstractThe present work deals with the preparation and characterization of improved fire-retardant ethylene-acrylate foams. A commercial formulation, usually employed in the cable industry sector, Casico, was modified using two different synergistic flame retardant (FR) systems: silica/zinc borate micro-sized particles (M) and montmorillonite/graphene nanoplatelets (N). The different composites were prepared by melt-blending and the foams by a compression-molding chemical foaming process (Casico-based foams). All Casico-based foams presented a mainly closed-cell structure. The presence of the nanoparticles system (N) promoted the formation of microcellular foams, with cell sizes lower than 100 µm, and narrow cell distributions. Nevertheless, when both flame retardant systems were added a higher cell collapse was noticed. Due to the foam's Casico-N structure and the presence of the stiff layered nanoparticles an increase of the temperature of ß and a relaxations and specific loss modulus was registered for that foam respect to the Casico foam. In a general way, the Casico-based foams presented a thermal decomposition behavior similar to that of unfoamed Casico. Only a slight increase of the thermal stability of the step associated to the ionomer decomposition was observed respect to the Casico. Significant fire behavior improvements were observed for Casico-M-N foam. Specifically, this foam showed the lowest value of PHRR (peak of heat release rate), EHC (effective heat of combustion) and FIGRA (fire index growth rate), having therefore the lowest flammability, even lower than Casico unfoamed material.
dc.format.extent9 p.
dc.language.isoeng
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subjectÀrees temàtiques de la UPC::Enginyeria dels materials::Assaig de materials
dc.subjectÀrees temàtiques de la UPC::Enginyeria dels materials::Materials plàstics i polímers
dc.subject.lcshPolymers--Fire testing
dc.subject.otherCone calorimeter
dc.subject.otherDMTA
dc.subject.otherFlame retardancy
dc.subject.otherNanoparticles
dc.subject.otherPolymer foams
dc.subject.otherThermal stability
dc.titleEnhanced fire behavior of Casico-based foams
dc.typeArticle
dc.subject.lemacPolímers -- Assaigs de comportament davant el foc
dc.contributor.groupUniversitat Politècnica de Catalunya. POLY2 - Polyfunctional polymeric materials
dc.identifier.doi10.1016/j.polymdegradstab.2016.03.029
dc.description.peerreviewedPeer Reviewed
dc.relation.publisherversionhttp://www.sciencedirect.com/science/article/pii/S014139101630088X
dc.rights.accessOpen Access
drac.iddocument18732344
dc.description.versionPostprint (author's final draft)
upcommons.citation.authorDe Redondo, V., De Sousa Pais, M., Velasco J.I.
upcommons.citation.publishedtrue
upcommons.citation.publicationNamePolymer degradation and stability
upcommons.citation.volume128
upcommons.citation.startingPage260
upcommons.citation.endingPage268


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