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Origin of high activity and selectivity of CuO/CeO2 catalysts prepared by solution combustion synthesis in CO-PROX reaction
dc.contributor.author | Barbato, P.S. |
dc.contributor.author | Colussi, Sara |
dc.contributor.author | Di Benedetto, A. |
dc.contributor.author | Landi, Giada |
dc.contributor.author | Lisi, L. |
dc.contributor.author | Llorca Piqué, Jordi |
dc.contributor.author | Trovarelli, Alessandro |
dc.contributor.other | Universitat Politècnica de Catalunya. Departament d'Enginyeria Química |
dc.date.accessioned | 2017-01-25T09:45:41Z |
dc.date.issued | 2016-06-23 |
dc.identifier.citation | Barbato, P., Colussi, S., Di Benedetto, A., Landi, G., Lisi, L., Llorca, J., Trovarelli, A. Origin of high activity and selectivity of CuO/CeO2 catalysts prepared by solution combustion synthesis in CO-PROX reaction. "The journal of physical chemistry. Part C, nanomaterials and interfaces", 23 Juny 2016, vol. 120, núm. 24, p. 13039-13048. |
dc.identifier.issn | 1932-7447 |
dc.identifier.uri | http://hdl.handle.net/2117/99997 |
dc.description.abstract | A CuO/CeO2 catalyst with 4 wt % CuO nominal content has been prepared by solution combustion synthesis (SCS) and characterized by ICP-MS, BET surface area analysis, XPS, HRTEM, and H-2, and/or CO TPR. The catalyst, showing a rather homogeneous distribution of copper that strongly interacts with ceria, has been tested in CO-PROX reaction. The enhanced performance of the catalyst compared to that of an impregnated sample with the same copper loading has been explained by modeling the experimental CO2 temperature-programmed desorption (TPD) curve, which allowed the determination and quantification of different active sites. The temperature range of activity and the ratio of the amount of sites activating CO and H-2 oxidation, respectively, estimated for the two catalysts through the model explain the superior performance of the sample prepared by SCS despite its lower surface area. |
dc.format.extent | 10 p. |
dc.language.iso | eng |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
dc.subject | Àrees temàtiques de la UPC::Enginyeria química |
dc.subject | Àrees temàtiques de la UPC::Enginyeria química::Química inorgànica |
dc.subject.lcsh | Catalysts |
dc.subject.lcsh | Combustion |
dc.subject.other | Oxide composite catalysts |
dc.subject.other | Preferential oxidation |
dc.subject.other | carbon-monoxide |
dc.subject.other | Cuo-ceo2 catalysts |
dc.subject.other | Excess hydrogen |
dc.subject.other | Redox properties |
dc.subject.other | H-2-rich gases |
dc.subject.other | Performance |
dc.subject.other | Methane |
dc.subject.other | Kinetics |
dc.title | Origin of high activity and selectivity of CuO/CeO2 catalysts prepared by solution combustion synthesis in CO-PROX reaction |
dc.type | Article |
dc.subject.lemac | Catalitzadors |
dc.subject.lemac | Combustió |
dc.contributor.group | Universitat Politècnica de Catalunya. NEMEN - Nanoenginyeria de materials aplicats a l'energia |
dc.identifier.doi | 10.1021/acs.jpcc.6b02433 |
dc.relation.publisherversion | http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.6b02433 |
dc.rights.access | Restricted access - publisher's policy |
local.identifier.drac | 18786728 |
dc.description.version | Postprint (author's final draft) |
dc.date.lift | 10000-01-01 |
local.citation.author | Barbato, P.; Colussi, S.; Di Benedetto, A.; Landi, G.; Lisi, L.; Llorca, J.; Trovarelli, A. |
local.citation.publicationName | The journal of physical chemistry. Part C, nanomaterials and interfaces |
local.citation.volume | 120 |
local.citation.number | 24 |
local.citation.startingPage | 13039 |
local.citation.endingPage | 13048 |
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