Manufacturing of nano-enhanced shape stabilized phase change materials with montmorillonite by Banbury oval rotor mixer for buildings applications
Cita com:
hdl:2117/386689
Document typeArticle
Defense date2022-11-01
PublisherElsevier
Rights accessOpen Access
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Attribution 4.0 International
Abstract
The use of adequate thermal energy storage (TES) systems has shown the potential to increase energy efficiency in many fields, such as the building sector. Shape-stabilized phase change materials (SS-PCMs) have attracted attention to address one of the key barriers of phase change materials (PCMs), the leakage during the liquid state, that nowadays limits its applicability. However, SS-PCMs still have drawbacks to overcome, such as poor fire reaction and thermal stability. In the present study, polymeric SS-PCMs are nano-enhanced with layered silicates to overcome these drawbacks. The new shape-stabilized nano-enhanced phase change material (SS-NEPCM) is based on ethylene propylene diene monomer (EPDM) as a polymeric matrix, palmitic acid (PA) as PCM and montmorillonite (MMT) as the layered silicate. An innovative method based on a Banbury mixer was used to prepare it, which is an industrially scalable fabrication method. To evaluate the effect of each component, eight different formulations were prepared: pure EPDM, EPDM with MMT additions (1 wt%, 3 wt% and 5 wt%), EPDM with PA additions (5 wt% and 10 wt%) and EPDM with MMT (3 wt%) and PA additions (5 wt% and 10 wt%). The composite materials obtained were not degraded by processing as FT-IR results show. The results obtained by X-ray diffraction showed that an ordered intercalated morphology is formed between EPDM chains and MMT. Thermogravimetric experimental results revealed an increase in the thermal stability of SS-NEPCM as a result of the barrier effect provided by MMT. Moreover, SS-NEPCM fire resistance was improved with a great reduction or avoidance of the dripping phenomenon.
CitationSalgado-Pizarro, R. [et al.]. Manufacturing of nano-enhanced shape stabilized phase change materials with montmorillonite by Banbury oval rotor mixer for buildings applications. "Journal of energy storage", 1 Novembre 2022, vol. 55, part A, núm. article 105289.
ISSN2352-152X
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