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Evaluating the potential of ozone in creating functional groups on cellulose
dc.contributor.author | Valls Vidal, Cristina |
dc.contributor.author | Cusola Aumedes, Oriol |
dc.contributor.author | Roncero Vivero, María Blanca |
dc.contributor.other | Universitat Politècnica de Catalunya. Departament d’Enginyeria Gràfica i de Disseny |
dc.date.accessioned | 2022-09-30T09:40:28Z |
dc.date.available | 2022-09-30T09:40:28Z |
dc.date.issued | 2022-08-01 |
dc.identifier.citation | Valls, C.; Cusola, O.; Roncero, M.B. Evaluating the potential of ozone in creating functional groups on cellulose. "Cellulose", 1 Agost 2022, vol. 29, núm. 12, p. 6595-6610. |
dc.identifier.issn | 1572-882X |
dc.identifier.uri | http://hdl.handle.net/2117/373762 |
dc.description.abstract | Several eucalyptus pulps (85% of cellulose) with different lignin and HexA content (unbleached, TCF and ECF) as well as cotton linters (97% of cellulose) were treated with ozone (at different pH and ozone doses) in order to modify its fibre-components. Special interest was given in the introduction of functional groups in carbohydrates. The presence of these groups was mainly identified by the chain scissions due to carbonyl groups (CSC=O) produced in cellulose during viscosity measurement. At a dose of 0.5% odp of ozone, the greatest amount of CSC=O (0.5) was created at acidic pH and with the ECF pulp, followed by the TCF (0.3) and by the unbleached (0.2). The same CSC=O (0.2) was obtained in cotton pulp. In this pulp, the ozone concentration had to be increased for the treatment to be effective. A further increase in the accessibility in both pulps was achieved by applying a washing stage between two ozone stages at 0.5% (0.5¿+¿0.5). With this treatment, the CSC=O was increased to 5.3 in the ECF, to 0.8 in the TCF and only to 0.3 in cotton. Brightness reversion and the amount of DNPH consumed were also used to verify the presence of functional groups. At 0.5¿+¿0.5, brightness reversion was increased from 16 to 55% in ECF, from 27 to 46% in TCF and from 7 to 31% in cotton. Therefore, it is shown that functional groups can be introduced by ozone in carbohydrates, but this effect strongly depends on the lignin, HexA and hemicellulose content |
dc.description.sponsorship | This publication is part of the PID2020-114070RB-I00 (CELLECOPROD) project, funded by MCIN/AEI/10.13039/501100011033. Authors are grateful to Torraspapel S.A. (Zaragoza, Spain), ENCE (Pontevedra, Spain) and CELESA (Tortosa, Spain) for supplying the pulp used. Special thanks are also due to the Serra Hunter Fellow to Oriol Cusola |
dc.format.extent | 16 p. |
dc.language.iso | eng |
dc.publisher | Springer |
dc.rights | Attribution 4.0 International |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ |
dc.subject | Àrees temàtiques de la UPC::Enginyeria paperera::Primeres matèries papereres |
dc.subject.lcsh | Cellulose |
dc.subject.lcsh | Papermaking |
dc.subject.lcsh | Polysaccharides |
dc.subject.lcsh | Viscosity |
dc.subject.lcsh | Ozone |
dc.subject.other | Cellulose |
dc.subject.other | Functional groups |
dc.subject.other | Hemicelluloses |
dc.subject.other | Hexenuronic acids |
dc.subject.other | Viscosity |
dc.subject.other | Ozone |
dc.title | Evaluating the potential of ozone in creating functional groups on cellulose |
dc.type | Article |
dc.subject.lemac | Cel·lulosa |
dc.subject.lemac | Paper -- Fabricació |
dc.subject.lemac | Polisacàrids |
dc.subject.lemac | Viscositat |
dc.subject.lemac | Ozó |
dc.contributor.group | Universitat Politècnica de Catalunya. CELBIOTECH - Grup de Recerca: Enginyeria Paperera |
dc.identifier.doi | 10.1007/s10570-022-04694-4 |
dc.relation.publisherversion | https://link.springer.com/article/10.1007/s10570-022-04694-4 |
dc.rights.access | Open Access |
local.identifier.drac | 34207667 |
dc.description.version | Postprint (published version) |
dc.relation.projectid | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-114070RB-I00/ES/TRANSFORMACION DE MATERIALES CELULOSICOS EN BIOPRODUCTOS AVANZADOS Y ECOLOGICOS/ |
local.citation.author | Valls, C.; Cusola, O.; Roncero, M.B. |
local.citation.publicationName | Cellulose |
local.citation.volume | 29 |
local.citation.number | 12 |
local.citation.startingPage | 6595 |
local.citation.endingPage | 6610 |
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