POL - Polímers Industrials Avançats i Biopolímers Tecnològics
Les activitats del grup es centren en tres línies I+D, totes elles dirigides al desenvolupament de materials amb propietats tècniques avançades, per a la seva utilització en noves aplicacions per als sectors plàstic i farmacèutic. Aquesta recerca inclou la síntesi o biosíntesi dels polímers, la seva caracterització química i estructural, i l'avaluació de les propietats tèrmiques i mecàniques, així com la seva degradació en tres àrees diferents: polímers industrials, polímers sostenibles i polímers produïts per biosíntesi. També es fan diferents
The group carries out research on polymers of interest to industry (polyesters, polyurethanes, polyamides and polycarbonates) based on natural products that are easily accessible (mostly carbohydrates), with the aim of achieving sustainable new polymers with advanced properties that can replace traditional petroleum-based plastics. It also carries out research on biopolymers from microbial biosynthesis that are then modified for biomedical applications as membranes or drug delivery systems.
The group carries out research on polymers of interest to industry (polyesters, polyurethanes, polyamides and polycarbonates) based on natural products that are easily accessible (mostly carbohydrates), with the aim of achieving sustainable new polymers with advanced properties that can replace traditional petroleum-based plastics. It also carries out research on biopolymers from microbial biosynthesis that are then modified for biomedical applications as membranes or drug delivery systems.
Col·leccions
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Articles de revista [71]
Enviaments recents
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Hydrolytic degradation of D-mannitol-based polyurethanes
(2018-07-01)
Article
Accés restringit per política de l'editorialThe capacity of redox D-mannitol-based polyurethanes to modulate the glutathione response under physiological conditions, as well as their effectiveness for sustained and site-specific drug release in the gastrointestinal ... -
Isomannide-containing poly(butylene 2,5-furandicarboxylate) copolyesters via ring opening polymerization
(American Chemical Society (ACS), 2018-05-08)
Article
Accés restringit per política de l'editorialCyclic oligomers of isomannide 2,5-furandicarboxylate were synthesized using the high dilution condensation method. A mixture of dimer, trimer, and tetramer species largely enriched in dimer was obtained. These cyclic ... -
Partially renewable poly(butylene 2,5-furandicarboxylate-co-isophthalate) copolyesters obtained by ROP
(Multidisciplinary Digital Publishing Institute (MDPI), 2018-04-28)
Article
Accés obertCyclic butylene furandicarboxylate (c(BF)n) and butylene isophthalate (c(BI)n) oligomers obtained by high dilution condensation reaction were polymerized in bulk at 200 °C with Sn(Oct)2 catalyst via ring opening polymerization ... -
Validation of smart nanoparticles as controlled drug delivery systems: loading and pH-dependent release of pilocarpine
(American Chemical Society (ACS), 2017-09-25)
Article
Accés obertMicelles are good devices for use as controlled drug delivery systems because they exhibit the ability to protect the encapsulated substance from the routes of degradation until they reach the site of action. The present ... -
Hydroxyl-functionalized amphiphilic triblock copolyesters made of tartaric and lactic acids: Synthesis and nanoparticle formation
(2018-05-01)
Article
Accés restringit per política de l'editorialBio-based triblock copolyesters were synthesized by ring-opening polymerization of l-lactide in solution using a hydroxyl-ended polytartrate as di-functional macroinitiator. This telechelic polyester with a Mn about ... -
Blocky poly(epsilon-caprolactone-co-butylene 2,5-furandicarboxylate) copolyesters via enzymatic ring opening polymerization
(2018-02-01)
Article
Accés restringit per política de l'editorialCyclic oligo(butylene 2,5-furandicarboxylate) and e-caprolactone were copolymerized in bulk at 130-150 ºC by enzymatic ring opening polymerization using CALB as catalyst. Copolyesters within a wide range of compositions ... -
Antibacterial films made of ionic complexes of poly(y-glutamic acid) and ethyl lauroyl arginate
(2017-12-24)
Article
Accés obert© 2017 by the author. The biocide agent LAE (ethyl aN-lauroyl l-arginate chloride) was coupled with poly(y-glutamic acid) (PGGA) to form stable ionic complexes with LAE:PGGA ratios of 1 and 0.5. The nanostructure adopted ... -
Modulating the Tg of poly(alkylene succinate)s by inserting bio-based aromatic units via ring-opening copolymerization
(2017-12-12)
Article
Accés obertTwo series of aliphatic-aromatic copolyesters derived from succinic and 2,5-furandicarboxylic acids, and di-O-2-(hydroxyethyl) resorcinol as diol substituent of either 1,4-butanediol or ethylene glycol, respectively, were ... -
Poly(butylene succinate-ran-epsilon-caprolactone) copolyesters: Enzymatic synthesis and crystalline isodimorphic character
(2017-10-01)
Article
Accés restringit per política de l'editorialIn this paper, the preparation of PBS-ran-PCL copolyesters by enzymatic ring opening polymerization is presented for the first time. The copolyesters were produced in a wide composition range and free of metallic contaminants, ... -
A green strategy for the synthesis of poly(ethylene succinate) and its copolyesters via enzymatic ring opening polymerization
(2017-10)
Article
Accés restringit per política de l'editorialPoly(ethylene succinate) (PES) with weight-average molecular weight above 60,000 g mol-1 was efficiently obtained by enzymatic ring opening polymerization of cyclic oligo(ethylene succinate)s c(ES)n, which in turn were ... -
Triblock copolyesters derived from lactic acid and glucose: synthesis, nanoparticle formation and simulation
(2017-07-01)
Article
Accés restringit per política de l'editorialABA triblock copolyesters were synthesized by ring-opening polymerization (ROP) of l-lactide in solution initiated by a telechelic d-glucose-based polyester macroinitiator. The macroinitiator with a number-average molecular ... -
Ionic complexes of poly(gamma-glutamic acid) with alkyltrimethylphosphonium surfactants
(Elsevier, 2017-05-05)
Article
Accés restringit per política de l'editorialA series of ionic complexes with a comb-like architecture and a nearly stoichiometric composition were prepared from bacterial poly(gamma,dl-glutamic acid) (PGGA) and alkyltrimethyl phosphonium bromides (nATMP·Br) bearing ...
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