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dc.contributor.authorHermassi, Mehrez
dc.contributor.authorValderrama Angel, César Alberto
dc.contributor.authorQuerol, Xavier
dc.contributor.authorHarrouch Batis, Narjes
dc.contributor.authorCortina Pallás, José Luís
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.date.accessioned2021-01-13T11:41:07Z
dc.date.issued2020-08-20
dc.identifier.citationHermassi, M. [et al.]. Phosphate recovery from aqueous solution by K-zeolite synthesized from fly ash for subsequent valorisation as slow release fertilizer. "Science of the total environment", 20 Agost 2020, vol. 731, p. 139002/1-139002/14.
dc.identifier.issn0048-9697
dc.identifier.urihttp://hdl.handle.net/2117/335260
dc.description.abstractThe sorption of phosphate by K-zeolites synthesized from fly ash (FA) by hydrothermal conversion is investigated in this study. The aim is the synthesis of Ca bearing K-zeolites to recover phosphate from urban and industrial wastewater effluents. The loaded zeolites are considered as a by-products rich in essential nutrients such K and P (KP1) with a potential use as slow release fertilizer. A number of synthesis conditions (temperature, KOH-solution/FA ratio, KOH concentration, and activation time) were applied on two FA samples (FA-TE and FA-LB) with similar glass content but different content of crystalline phases, to optimize the synthesis of a zeolitic sorbent suitable for the subsequent phosphate uptake. Merlinoite and W rich zeolitic products synthesized from FA-LB and FA-TE were found to have sorption properties for phosphate removal. A maximum phosphate sorption capacity of 250 mgP-PO4/g and 142 mgP-PO4/g for the zeolitic products selected (KP1-LB and KP1-TE, respectively) was achieved. The dominant phosphate sorption mechanism, in the pH range (6–9) of treated wastewater effluents, indicated that sorption proceeds via a diffusion-controlled process involving phosphate ions coupled with calcium supply dissolution from K-zeolitic products and subsequent formation of brushite (CaHPO4 2H2O(s)). The phosphate loaded sorbent containing a relatively soluble phosphate mineral is appropriate for its use as a synthetic slow release fertilizer. The simultaneous valorisation of fly ash waste and the P recovery from treated wastewaters effluents, (a nutrient with scarce natural resources and low supply) by obtaining a product with high potential for land restoration and agriculture will contribute to develop one example of circularity
dc.language.isoeng
dc.publisherElsevier
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Spain
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subjectÀrees temàtiques de la UPC::Enginyeria química
dc.subject.lcshFly ash
dc.subject.lcshPhosphates
dc.subject.otherPotassium zeolite
dc.subject.otherFly ash
dc.subject.otherPhosphate recovery
dc.subject.otherTreated wastewater
dc.subject.otherSorption
dc.subject.otherBrushite
dc.titlePhosphate recovery from aqueous solution by K-zeolite synthesized from fly ash for subsequent valorisation as slow release fertilizer
dc.typeArticle
dc.subject.lemacCendres volants
dc.subject.lemacZeolites
dc.subject.lemacFosfats
dc.subject.lemacAigües residuals -- Depuració -- Eliminació de fosfats
dc.contributor.groupUniversitat Politècnica de Catalunya. R2EM - Resource Recovery and Environmental Management
dc.identifier.doi10.1016/j.scitotenv.2020.139002
dc.description.peerreviewedPeer Reviewed
dc.relation.publisherversionhttps://www.sciencedirect.com/science/article/pii/S0048969720325195
dc.rights.accessRestricted access - publisher's policy
local.identifier.drac28894970
dc.description.versionPostprint (author's final draft)
dc.date.lift2022-08-20
local.citation.authorHermassi, M.; Valderrama, C.; Querol, X.; Harrouch, N.; Cortina, J.
local.citation.publicationNameScience of the total environment
local.citation.volume731
local.citation.startingPage139002/1
local.citation.endingPage139002/14


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Attribution-NonCommercial-NoDerivs 3.0 Spain
Except where otherwise noted, content on this work is licensed under a Creative Commons license : Attribution-NonCommercial-NoDerivs 3.0 Spain