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dc.contributor.authorde Arespacochaga, N.
dc.contributor.authorValderrama Angel, César Alberto
dc.contributor.authorMesa, C.
dc.contributor.authorBouchy, Lynne
dc.contributor.authorCortina Pallás, José Luís
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.date.accessioned2015-03-20T13:15:27Z
dc.date.created2014-11-01
dc.date.issued2014-11-01
dc.identifier.citationde Arespacochaga, N. [et al.]. Biogas deep clean-up based on adsorption technologies for solid oxide fuel cell applications. "Chemical engineering journal", 01 Novembre 2014, vol. 255, p. 593-603.
dc.identifier.issn1385-8947
dc.identifier.urihttp://hdl.handle.net/2117/26893
dc.description.abstractBiogas from anaerobic digestion is a powerful renewable fuel that can be used as a feedstock for fuel cell systems. A biogas deep treatment was installed and operated at pilot plant level in a Waste Water Treatment Plant (WWTP) in Spain in order to demonstrate the integration opportunities with Solid Oxide Fuel Cell (SOFC) technologies. The three-stage polishing system based on adsorption consisted of: (i) a regenerable iron-based adsorbent unit to remove H2S, (ii) a biogas drying unit to remove moisture and (iii) an activated carbon unit to remove the remaining trace components (siloxanes, linear and aromatic hydrocarbons). The biogas entering the polishing system was previously treated in a biotrickling filter for primary H2S abatement. Removal efficiencies on the iron-based adsorbent were over 99% and adsorption capacity was calculated to be of 21%wt. An adsorption mechanism for H2S chemisorption oriented to oxidation to elemental sulphur rather than to crystalline FeS(s) was proposed and could explain the low efficiency of the regeneration process. The remaining contaminant traces were efficiently removed in the drying and activated carbon unit and concentration levels below 0.1 mg/Nm(3) were obtained. A roll-up phenomenon with siloxane D4, which was responsible of adsorption breakthrough on the activated carbon filters, was postulated; and leaded to an overall adsorption capacity of 2%wt. The economic assessment concluded that the cascade configuration of an upstream H2S abatement followed by downstream adsorption technologies, compared to stand-alone adsorption systems, divides the overall treatment cost by three; increasing the profitability of biogas-powered fuel cell projects. (C) 2014 Elsevier B.V. All rights reserved.
dc.format.extent11 p.
dc.language.isoeng
dc.subjectÀrees temàtiques de la UPC::Enginyeria química
dc.subjectÀrees temàtiques de la UPC::Energies
dc.subject.lcshBiogas
dc.subject.lcshCarbon, Activated
dc.subject.lcshFuel cell
dc.subject.otherBiogas desulfurization
dc.subject.otherIron-based adsorbent
dc.subject.otherActivated carbon
dc.subject.otherSiloxanes removal
dc.subject.otherFuel cell
dc.subject.otherHYDROGEN-SULFIDE
dc.subject.otherACTIVATED CARBON
dc.subject.otherLANDFILL GAS
dc.subject.otherSILOXANES
dc.subject.otherH2S
dc.subject.otherBIOFILTRATION
dc.subject.otherIMPURITIES
dc.subject.otherOXIDATION
dc.subject.otherENERGY
dc.subject.otherDESULFURIZATION
dc.titleBiogas deep clean-up based on adsorption technologies for solid oxide fuel cell applications
dc.typeArticle
dc.subject.lemacPiles de combustible
dc.subject.lemacBiogàs
dc.subject.lemacCarbó activat
dc.contributor.groupUniversitat Politècnica de Catalunya. SETRI - Grup de Tècniques de Separació i Tractament de Residus Industrials
dc.identifier.doi10.1016/j.cej.2014.06.072
dc.rights.accessRestricted access - publisher's policy
drac.iddocument15229585
dc.description.versionPostprint (published version)
dc.date.lift10000-01-01
upcommons.citation.authorde Arespacochaga, N.; Valderrama, C.; Mesa, C.; Bouchy, L.; Cortina, J.
upcommons.citation.publishedtrue
upcommons.citation.publicationNameChemical engineering journal
upcommons.citation.volume255
upcommons.citation.startingPage593
upcommons.citation.endingPage603


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