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dc.contributor.authorbasas jaumandreu, josep
dc.contributor.authorLópez Fernandez, Jordi
dc.contributor.authorHeras Cisa, F. Xavier de las
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament d'Enginyeria Minera i Recursos Naturals
dc.date.accessioned2015-03-20T12:25:31Z
dc.date.available2015-03-20T12:25:31Z
dc.date.created2014-12
dc.date.issued2014-12
dc.identifier.citationbasas, J.; López, J.; Heras, F. Resorcinol and m-guaiacol alkylated derivatives and asymmetrical secondary alcohols in the leaves from Tamarix canariensis. "Phytochemistry Letters", Desembre 2014, vol. 10, p. 240-248.
dc.identifier.issn1874-3900
dc.identifier.urihttp://hdl.handle.net/2117/26886
dc.description.abstractIn the study of leaves from the halotolerant saltcedar (Tamarix canariensis Willd.) we have found a new abundant source of resorcinolic as well as guaiacolic compounds. A homologous series of 5-n-alkylresorcinols with long side alkyl chain reported previously in the literature almost exclusively in cereals are described here for the first time in Tamaricaceae. These polyketide derived phenolic compounds are characterized by a series ranging from n-C15 to n-C27 and maximizing at n-C21 including non-negligible amounts of the even-numbered homologues. We also have characterized for the first time as natural compounds a homologous series of 5-n-alkylguaiacols similarly constituted by an odd-numbered alkyl chain linked to the benzene ring at position 5. They also include a hydroxyl group at carbon 1 of the phenolic nucleus and a methoxy group at position 3. The homologues are in the range of 13-27 carbon atoms (Cmax at C21). Finally, we firstly report in Tamaricaceae eight series of unsymmetrical secondary alcohols ranging from n-C25 to n-C35 with hentriacontan-12-ol as the major homologue. This saltcedar leaves waxes contained high amounts of alkylresorcinol (17,2 g/kg dw), alkylguaiacol (14,4 g/kg dw) and secondary alcohols (44,4 g/kg dw).
dc.format.extent9 p.
dc.language.isoeng
dc.subjectÀrees temàtiques de la UPC::Enginyeria química::Química del medi ambient
dc.subject.otherTamarix canariensis
dc.subject.othersalcedar
dc.subject.othertamaricaceae
dc.subject.otherleaf epicuticular waxes
dc.subject.otheralkylresorcinol
dc.subject.otheralkylguaiacols secondary linear alcohols GC-MS
dc.subject.otherTMS-ether-derivatives
dc.titleResorcinol and m-guaiacol alkylated derivatives and asymmetrical secondary alcohols in the leaves from Tamarix canariensis
dc.typeArticle
dc.contributor.groupUniversitat Politècnica de Catalunya. TRAGASOL - Grup de Tractament Biològic de Contaminants Gasosos i Olors
dc.identifier.doi10.1016/j.phytol.2014.10.009
dc.description.peerreviewedPeer Reviewed
dc.relation.publisherversionhttp://www.sciencedirect.com/science/article/pii/S1874390014001852
dc.rights.accessOpen Access
drac.iddocument15533190
dc.description.versionPostprint (author’s final draft)
upcommons.citation.authorbasas, J.; López, J.; Heras, F.
upcommons.citation.publishedtrue
upcommons.citation.publicationNamePhytochemistry Letters
upcommons.citation.volume10
upcommons.citation.startingPage240
upcommons.citation.endingPage248


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