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Rapid functionalisation of cellulose-based materials using a mixture containing laccase activated lauryl gallate and sulfonated lignin
dc.contributor.author | Cusola Aumedes, Oriol |
dc.contributor.author | Valls Vidal, Cristina |
dc.contributor.author | Vidal Lluciá, Teresa |
dc.contributor.author | Roncero Vivero, María Blanca |
dc.contributor.other | Universitat Politècnica de Catalunya. Departament d'Enginyeria Tèxtil i Paperera |
dc.date.accessioned | 2015-02-11T10:07:34Z |
dc.date.created | 2014-01-11 |
dc.date.issued | 2014-01-11 |
dc.identifier.citation | Cusola, O. [et al.]. Rapid functionalisation of cellulose-based materials using a mixture containing laccase activated lauryl gallate and sulfonated lignin. "Holzforschung", 11 Gener 2014, vol. 68, núm. 6, p. 631-639. |
dc.identifier.issn | 0018-3830 |
dc.identifier.uri | http://hdl.handle.net/2117/26295 |
dc.description.abstract | An innovative method has been developed for the surface hydrophobisation of cellulose-based materials by coating it with a functionalised solution (FS), in which sonicated lauryl gallate (LG, dodecyl 3,4,5,-trihydroxybenzoate), sulfonated kraft lignin, and the enzyme laccase play a pivotal role. The rapid treatment with FS increases the hydrophobicity of cellulose sheets considerably. The FS retention on the paper surface was analysed as a function of refining and application of additives. The properties of the functionalised sheets were assessed by the water-drop test (WDT), and the surface free energy (SFE) was determined via contact angle (CA) measurements in a goniophotometer. WDT resulted in long absorption times of up to 4000 s and CA values were around 130°. Functionalised solution modification of eucalyptus paper sheets decreased SFE essentially from 55 mJ m-2 to 10 mJ m-2. ATR-FTIR suggested that FS was grafted onto the cellulosic sheets. The stability of FS and the control solutions were characterised by Z potential and light scattering measurements. The functionalised solution method is a one-step roll-to-roll process, which is easy to perform also in industrial application without additional investments. It has a potential to substitute the traditional hydrophobing processes. |
dc.format.extent | 9 p. |
dc.language.iso | eng |
dc.subject | Àrees temàtiques de la UPC::Enginyeria paperera::Primeres matèries papereres::Cel·lulosa |
dc.subject.lcsh | Cellulose |
dc.subject.lcsh | Lignosulfonates |
dc.subject.lcsh | Fibers |
dc.subject.lcsh | Paper |
dc.subject.other | cellulose |
dc.subject.other | dispersants |
dc.subject.other | functionalisation |
dc.subject.other | hydrophobicity |
dc.subject.other | laccase treatment |
dc.subject.other | lignosulfonates |
dc.title | Rapid functionalisation of cellulose-based materials using a mixture containing laccase activated lauryl gallate and sulfonated lignin |
dc.type | Article |
dc.subject.lemac | Cel·lulosa per a paper |
dc.subject.lemac | Lignocel·lulosa |
dc.subject.lemac | Fibres |
dc.subject.lemac | Paper |
dc.contributor.group | Universitat Politècnica de Catalunya. CELBIOTECH - Grup de Recerca: Enginyeria Paperera |
dc.identifier.doi | 10.1515/hf-2013-0128 |
dc.relation.publisherversion | http://www.degruyter.com/view/j/hfsg.2014.68.issue-6/hf-2013-0128/hf-2013-0128.xml |
dc.rights.access | Restricted access - publisher's policy |
local.identifier.drac | 15072475 |
dc.description.version | Postprint (published version) |
dc.date.lift | 10000-01-01 |
local.citation.author | Cusola, O.; Valls, C.; Vidal, T.; Roncero, M. |
local.citation.publicationName | Holzforschung |
local.citation.volume | 68 |
local.citation.number | 6 |
local.citation.startingPage | 631 |
local.citation.endingPage | 639 |
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