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dc.contributor.authorFernández Francos, Xavier
dc.contributor.authorSerra Albet, Àngels
dc.contributor.authorRamis Juan, Xavier
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament de Màquines i Motors Tèrmics
dc.date.accessioned2014-07-25T09:23:32Z
dc.date.created2014-04-01
dc.date.issued2014-04-01
dc.identifier.citationFernández, X.; Serra, À.; Ramis, X. Comparative analysis of stochastic network build-up methods for the curing of epoxy-anhydride thermosets. "European polymer journal", 01 Abril 2014, vol. 53, p. 22-36.
dc.identifier.issn0014-3057
dc.identifier.urihttp://hdl.handle.net/2117/23609
dc.description.abstractThe network build-up of epoxy-anhydride thermosets has been studied using two different stochastic network build-up methods based on the random combination of primary chains or simple fragments. Explicit expressions for relevant statistic averages in the pregel and postgel states have been derived for both methods. The application of both methods to a living polymerization kinetic model leads to strong divergences in the vicinity of the critical conversion at gelation due to growing differences between the real primary chain distribution and the most probable distribution in the fragment model. However, the application of both methods to an initiator regeneration kinetic model leads to identical results because of the distribution of primary chains throughout the whole curing process is a most probable one. (C) 2014 Elsevier Ltd. All rights reserved.
dc.format.extent15 p.
dc.language.isoeng
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Spain
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subjectÀrees temàtiques de la UPC::Enginyeria dels materials::Materials plàstics i polímers
dc.subject.lcshPolymers
dc.subject.otherThermosets
dc.subject.otherGelation
dc.subject.otherNetwork build-up
dc.titleComparative analysis of stochastic network build-up methods for the curing of epoxy-anhydride thermosets
dc.typeArticle
dc.subject.lemacPolímers
dc.contributor.groupUniversitat Politècnica de Catalunya. TERFIQ - Grup de Termodinàmica i Fisico-Química
dc.identifier.doi10.1016/j.eurpolymj.2014.01.015
dc.rights.accessRestricted access - publisher's policy
local.identifier.drac14938751
dc.description.versionPostprint (published version)
dc.date.lift10000-01-01
local.citation.authorFernández, X.; Serra, À.; Ramis, X.
local.citation.publicationNameEuropean polymer journal
local.citation.volume53
local.citation.startingPage22
local.citation.endingPage36


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Attribution-NonCommercial-NoDerivs 3.0 Spain
Except where otherwise noted, content on this work is licensed under a Creative Commons license : Attribution-NonCommercial-NoDerivs 3.0 Spain