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dc.contributor.authorTorrades Carné, Francesc
dc.contributor.authorGarcía Montaño, Júlia
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.date.accessioned2014-07-18T10:22:21Z
dc.date.available2014-07-18T10:22:21Z
dc.date.created2014-01
dc.date.issued2014-01
dc.identifier.citationTorrades, F.; García-Montaño, J. Using central composite experimental design to optimize the degradation of real dye wastewater by Fenton and photo-Fenton reactions. "Dyes and pigments", Gener 2014, vol. 100, p. 184-189.
dc.identifier.issn0143-7208
dc.identifier.urihttp://hdl.handle.net/2117/23562
dc.description.abstractThis work focuses on the use of Fenton reagent and UV-irradiation, in a lab-scale experiment, for the treatment of real dye wastewater coming from a Spanish textile manufacturer. Response surface methodology and a 23 factorial design were used to evaluate the effects of the three independent variables considered for the optimization of the oxidative process: temperature, Fe (II) and H2O2 concentrations, for a textile wastewater generated during a dyeing process with chemical oxygen demand of 1705 mg L -1 O2 at pH = 3. Wastewater degradation was followed in terms of chemical oxygen demand reduction. In the optimization, the correlation coefficients for the model (R2) were 0.985 and 0.990 for Fenton and photo-Fenton treatments respectively. Optimum reaction conditions at pH = 3 and temperature = 298 K were [H2O2] = 73.5 mM and [Fe(II)] = 1.79 mM. The combination of Fenton, Fenton-like and photon-Fenton reactions has been proved to be highly effective for the treatment of such a type of wastewaters, and several advantages for this technique arise from the study. Under optimum conditions, 120 min of treatment resulted in a 62.9% and 76.3% reduction in chemical oxygen demand after Fenton and photo-Fenton treatments respectively.
dc.format.extent6 p.
dc.language.isoeng
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Spain
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subjectÀrees temàtiques de la UPC::Enginyeria química::Indústries químiques::Química tèxtil
dc.subjectÀrees temàtiques de la UPC::Enginyeria química::Indústria dels processos químics
dc.subject.lcshTextile chemistry
dc.subject.lcshOxidation-reduction reaction
dc.subject.otherAdvanced oxidation processes
dc.subject.otherCentral composite design
dc.subject.otherChemical oxygen demand reduction
dc.subject.otherFenton
dc.subject.otherPhotochemical reactions
dc.subject.otherReal dye wastewater
dc.titleUsing central composite experimental design to optimize the degradation of real dye wastewater by Fenton and photo-Fenton reactions
dc.typeArticle
dc.subject.lemacQuímica tèxtil -- Residus
dc.subject.lemacReacció d'oxidació-reducció
dc.contributor.groupUniversitat Politècnica de Catalunya. ENMA - Enginyeria del Medi Ambient
dc.identifier.doi10.1016/j.dyepig.2013.09.004
dc.rights.accessOpen Access
drac.iddocument13441974
dc.description.versionPreprint
upcommons.citation.authorTorrades, F.; García-Montaño, J.
upcommons.citation.publishedtrue
upcommons.citation.publicationNameDyes and pigments
upcommons.citation.volume100
upcommons.citation.startingPage184
upcommons.citation.endingPage189


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Except where otherwise noted, content on this work is licensed under a Creative Commons license: Attribution-NonCommercial-NoDerivs 3.0 Spain