Show simple item record

dc.contributor.authorFortuny Sanromá, Agustín
dc.contributor.authorColl Ausió, Mª Teresa
dc.contributor.authorKedari, Chandrashekhar S.
dc.contributor.authorSastre Requena, Ana María
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.date.accessioned2014-06-12T09:06:50Z
dc.date.available2014-06-12T09:06:50Z
dc.date.created2014-06
dc.date.issued2014-06
dc.identifier.citationFortuny, A. [et al.]. Effect of phase modifiers on boron removal by solvent extraction using 1,3 diolic compounds. "Journal of Chemical Technology and Biotechnology", Juny 2014, vol. 89, núm. 6, p. 858-865.
dc.identifier.issn1097-4660
dc.identifier.urihttp://hdl.handle.net/2117/23205
dc.description.abstractAbstract: BACKGROUND: Among the polyols, 1,3 diols are selective and efficient extractants for boron but significant solubility of these into aqueous solutions restricts their application in large scale separation processes. Solvent modifiers can be used to reduce extractant loss to the aqueous phase. Efficiency of the diolic extractants for boron separation have been tested in the presence of different solvent modifiers. RESULTS: Compared with other modifiers studied, decanol gives better stability to diolic molecules in the Kerosene phase and exhibits a reduced negative effect on the extraction of boron. Next to decanol, the low viscous 2,6-dimethyl-4-heptanone can be used as solvent modifier. In successive extraction studies, 2-butyl-2-ethyl-1,3-propanediol (BEPD) showed better stability among the diols studied in the presence of decanol in the organic phase. CONCLUSION: Quantitative removal of boron was achieved from industrial waste solutions such as a spent phosphate passivation bath and a cutting fluid, using 0.6 mol L-1 BEPD and 0.6 mol L-1 2,2,4-trimethyl-1,3-pentanediol (TMPD) in 25% decanol/Kerosene organic phase
dc.format.extent8 p.
dc.language.isoeng
dc.subjectÀrees temàtiques de la UPC::Enginyeria química::Química del medi ambient::Química de l'aigua
dc.subjectÀrees temàtiques de la UPC::Enginyeria química::Química física::Dissolucions
dc.subject.lcshBoron
dc.subject.lcshExtraction (Chemistry)
dc.subject.lcshLiquid-liquid equilibrium
dc.subject.lcshSolvent extraction
dc.subject.otherBoron removal
dc.subject.otherDiolic compounds
dc.subject.otherLiquid-liquid extraction
dc.subject.otherSolvent modifiers
dc.titleEffect of phase modifiers on boron removal by solvent extraction using 1,3 diolic compounds
dc.typeArticle
dc.subject.lemacExtracció (Química)
dc.subject.lemacEquilibri líquid-líquid
dc.subject.lemacExtracció per dissolvent
dc.subject.lemacBor
dc.contributor.groupUniversitat Politècnica de Catalunya. SETRI - Grup de Tècniques de Separació i Tractament de Residus Industrials
dc.identifier.doi10.1002/jctb.4322
dc.relation.publisherversionhttp://onlinelibrary.wiley.com/doi/10.1002/jctb.4322/full
dc.rights.accessOpen Access
drac.iddocument14917283
dc.description.versionPreprint
upcommons.citation.authorFortuny, A.; Coll, M.; C. S.; Sastre, A.
upcommons.citation.publishedtrue
upcommons.citation.publicationNameJournal of Chemical Technology and Biotechnology
upcommons.citation.volume89
upcommons.citation.number6
upcommons.citation.startingPage858
upcommons.citation.endingPage865


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record

All rights reserved. This work is protected by the corresponding intellectual and industrial property rights. Without prejudice to any existing legal exemptions, reproduction, distribution, public communication or transformation of this work are prohibited without permission of the copyright holder