Boosted CO2 reaction with methanol to yield dimethyl carbonate over Mg–Al hydrotalcite-silica lyogels

Stoian, D.C.; Taboada, E.; Llorca Piqué, Jordi; Molins, E.; Medina, F.; Segarra, A.M.

doi:10.1039/c3cc41298a

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Stoian, D.C.

Taboada, E.

Llorca Piqué, Jordi

Molins, E.

Medina, F.

Segarra, A.M.

Document typeArticle

Defense date2013-05-13

Rights accessRestricted access - publisher's policy

Except where otherwise noted, content on this work is licensed under a Creative Commons license : Attribution-NonCommercial-NoDerivs 3.0 Spain

Abstract

Nonimmobilized and immobilized Mg–Al hydrotalcite-like materials on silica lyogels were prepared and activated by calcination to be tested as catalysts in the direct carboxylation reaction of methanol. The HTs supportedon silica lyogels showedan important improvement andhigh stability in the direct synthesis reaction of DMC from CO2 and MeOH.

CitationStoian, D.C. [et al.]. Boosted CO2 reaction with methanol to yield dimethyl carbonate over Mg–Al hydrotalcite-silica lyogels. "Chemical communications", 13 Maig 2013, núm. 49, p. 5489-5491.

URIhttp://hdl.handle.net/2117/21404

DOI10.1039/c3cc41298a

ISSN1359-7345

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