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dc.contributor.authorFabregat Jové, Georgina
dc.contributor.authorAlemán Llansó, Carlos
dc.contributor.authorCasas Becerra, María Teresa
dc.contributor.authorArmelín Diggroc, Elaine Aparecida
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.date.accessioned2012-10-02T11:08:45Z
dc.date.created2012-04-26
dc.date.issued2012-04-26
dc.identifier.citationFabregat, G. [et al.]. Controlling the morphology of poly(N -cyanoethylpyrrole). "Journal of physical chemistry B", 26 Abril 2012, vol. 116, núm. 16, p. 5064-5070.
dc.identifier.issn1520-6106
dc.identifier.urihttp://hdl.handle.net/2117/16598
dc.description.abstractThe morphology of poly(N-cyanoethylpyrrole) has been controlled through the polymerization process. This polymer has been prepared by anodic polymerization, chemical oxidative polymerization in emulsion medium, and layer-by-layer templating polymerization. Anodic polymerization using LiClO4 as supporting electrolyte provides compact films, in which the oxidation degree is controlled through the thickness, useful for the microdetection of dopamine. Chemical polymerization using FeCl3 as oxidant agent results in very well-defined microspheres with porous internal structure, which may be useful in molecular loading and transport processes. Finally, the layer-by-layer templating technique produces core−shell particles of controlled size and thickness. Moreover, these core−shell particles can be easily converted in hollow microspheres by removing the template
dc.format.extent7 p.
dc.language.isoeng
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Spain
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subjectÀrees temàtiques de la UPC::Enginyeria química
dc.subject.lcshPolymerization
dc.subject.otherAnodic polymerization
dc.subject.otherChemical oxidative polymerization
dc.subject.otherChemical polymerization
dc.subject.otherControlled size
dc.subject.otherCore-shell particle
dc.subject.otherHollow microsphere
dc.subject.otherInternal structure
dc.subject.otherLayer-by-layers
dc.subject.otherMolecular loadings
dc.subject.otherOxidation degree
dc.subject.otherPolymerization process
dc.subject.otherSupporting electrolyte
dc.subject.otherTemplating polymerization
dc.subject.otherTemplating techniques
dc.subject.otherTransport process
dc.titleControlling the morphology of poly(N -cyanoethylpyrrole)
dc.typeArticle
dc.subject.lemacPolimerització
dc.contributor.groupUniversitat Politècnica de Catalunya. PSEP - Polimers Sintètics: Estructura i Propietats. Polimers Biodegradables.
dc.contributor.groupUniversitat Politècnica de Catalunya. IMEM - Innovació, Modelització i Enginyeria en (BIO) Materials
dc.identifier.doi10.1021/jp3008688
dc.description.peerreviewedPeer Reviewed
dc.relation.publisherversionhttp://pubs.acs.org/doi/pdfplus/10.1021/jp3008688
dc.rights.accessRestricted access - publisher's policy
local.identifier.drac10507383
dc.description.versionPostprint (published version)
dc.date.lift10000-01-01
local.citation.authorFabregat, G.; Alemán, C.; Casas, M.; Armelin, E.
local.citation.publicationNameJournal of physical chemistry B
local.citation.volume116
local.citation.number16
local.citation.startingPage5064
local.citation.endingPage5070


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Attribution-NonCommercial-NoDerivs 3.0 Spain
Except where otherwise noted, content on this work is licensed under a Creative Commons license : Attribution-NonCommercial-NoDerivs 3.0 Spain