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dc.contributor.authorLavilla Aguilar, Cristina
dc.contributor.authorAlla Bedahnane, Abdelilah
dc.contributor.authorMartínez de Ilarduya Sáez de Asteasu, Domingo Antxon
dc.contributor.authorBenito, Elena
dc.contributor.authorGarcía Martín, Maria de Gracia
dc.contributor.authorGalbis Pérez, Juan Antonio
dc.contributor.authorMuñoz Guerra, Sebastián
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.date.accessioned2012-07-05T09:51:55Z
dc.date.created2012-04-15
dc.date.issued2012-04-15
dc.identifier.citationLavilla, C. [et al.]. Carbohydrate-based copolyesters made from bicyclic acetalized galactaric acid. "Journal of polymer science. Part A, polymer chemistry", 15 Abril 2012, vol. 50, núm. 8, p. 1591-1604.
dc.identifier.issn0887-624X
dc.identifier.urihttp://hdl.handle.net/2117/16184
dc.description.abstractMixtures of the dimethyl esters of adipic acid and 2,3:4,5-di-O-methylene-galactaric acid (Galx) were made to react in the melt with either 1,6-hexanediol or 1,12-dodecanediol to produce linear polycyclic copolyesters with aldarate unit contents varying from 10 up to 90 mole %. The copolyesters had weight–average molecular weights in the ∼35,000–45,000 g mol−1 range and a random microstructure, and were thermally stable up to nearly 300 °C. They displayed Tg in the -50 to -7 °C range with values largely increasing with the content in galactarate units. All the copolyesters were semicrystalline with Tm between 20 and 90 °C but only those made from 1,12-dodecanediol were able to crystallize from the melt at a crystallization rate that decreased as the contents in the two comonomers approached each other. Copolyesters containing minor amounts of galactarate units adopted the crystal structure characteristic of aliphatic polyesters but a new crystal polymorph was formed when the cyclic sugar units became the majority. Stress–strain parameters were sensitively affected by composition of the copolyesters with the mechanical behavior changing from flexible/ductile to stiff/brittle with the replacement of adipate units by the galactarate units.
dc.format.extent14 p.
dc.language.isoeng
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Spain
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subjectÀrees temàtiques de la UPC::Enginyeria química
dc.subject.lcshPolyesters
dc.subject.lcshPolymerization
dc.titleCarbohydrate-based copolyesters made from bicyclic acetalized galactaric acid
dc.typeArticle
dc.subject.lemacPolièsters
dc.subject.lemacPolimerització
dc.contributor.groupUniversitat Politècnica de Catalunya. POL - Polímers Industrials Avançats i Biopolímers Tecnològics
dc.identifier.doi10.1002/pola.25930
dc.description.peerreviewedPeer Reviewed
dc.relation.publisherversionhttp://onlinelibrary.wiley.com/doi/10.1002/pola.25930/abstract
dc.rights.accessRestricted access - publisher's policy
drac.iddocument10656030
dc.description.versionPostprint (published version)
dc.relation.projectidinfo:eu-repo/grantAgreement/EC/FP7/226716/EU/European Light Sources Activities - Synchrotrons and Free Electron Lasers/ELISA
dc.date.lift10000-01-01
upcommons.citation.authorLavilla, C.; Alla, A.; Martinez de Ilarduya, A.; Benito, E.; García, M.G.; Galbis, J.; Muñoz, S.
upcommons.citation.publishedtrue
upcommons.citation.publicationNameJournal of polymer science. Part A, polymer chemistry
upcommons.citation.volume50
upcommons.citation.number8
upcommons.citation.startingPage1591
upcommons.citation.endingPage1604


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Except where otherwise noted, content on this work is licensed under a Creative Commons license: Attribution-NonCommercial-NoDerivs 3.0 Spain