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dc.contributor.authorArdanuy Raso, Mònica
dc.contributor.authorRodríguez-Pérez, Miguel Ángel
dc.contributor.authorSaja, José Antonio de
dc.contributor.authorVelasco Perero, José Ignacio
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament de Ciència dels Materials i Enginyeria Metal·lúrgica
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament d'Enginyeria Tèxtil i Paperera
dc.date.accessioned2012-04-25T12:10:01Z
dc.date.available2012-04-25T12:10:01Z
dc.date.created2012-04-10
dc.date.issued2012-04-10
dc.identifier.citationArdanuy, M. [et al.]. Foaming behavior, cellular structure and physical properties of polybenzoxazine foams. "Polymers for advanced technologies", 10 Abril 2012, vol. 23, núm. 5, p. 841-849.
dc.identifier.issn1042-7147
dc.identifier.urihttp://hdl.handle.net/2117/15759
dc.description.abstractIn this paper, polymer foams based on a benzoxazine resin have been successfully prepared using azodicarbonamide (ADC) as a chemical blowing agent and have been characterized regarding their foaming behavior, cellular structure, and physical properties. The effect of the ADC on the curing process of the resin was analyzed using differential scanning calorimetry and blowing agent decomposition was followed by thermogravitmetric analysis (TGA). The characterization of the cellular structure of the foamed samples was done using scanning electron microscopy. The mechanical properties of the foams were determined using compression tests and the thermal conductivity was assessed using the transient plane source method. The results indicated that the curing process and gas release took place in a similar time interval. The foams showed an isotropic cellular structure with relative densities in the range 0.35–0.60, and showed compressive strengths and compressive moduli in the range of 10–70 MPa and 400–1100 MPa, respectively. Thermal conductivities were in the range of 0.06–0.12 W m−1K−1. The findings in this paper demonstrate the possibility of producing polybenzoxazine foams using a simple process in which curing and foaming take place simultaneously. In addition, the mechanical characterization of these materials indicates that they are suitable for structural applications.
dc.format.extent9 p.
dc.language.isoeng
dc.subjectÀrees temàtiques de la UPC::Enginyeria dels materials::Materials plàstics i polímers
dc.subject.lcshPolybenzoxazine foams
dc.subject.lcshCuring (chemistry)
dc.subject.otherCuring behavior
dc.subject.otherFoaming behavior
dc.subject.otherFoams
dc.subject.otherPolybenzoxazine
dc.titleFoaming behavior, cellular structure and physical properties of polybenzoxazine foams
dc.typeArticle
dc.subject.lemacEscumes (Indústria química)
dc.contributor.groupUniversitat Politècnica de Catalunya. TECTEX - Grup de Recerca en Tecnologia Tèxtil
dc.contributor.groupUniversitat Politècnica de Catalunya. POLYCOM - Polimers i compòsits: tecnologia
dc.identifier.doi10.1002/pat.1978
dc.description.peerreviewedPeer Reviewed
dc.relation.publisherversionhttp://onlinelibrary.wiley.com/doi/10.1002/pat.1978/abstract
dc.rights.accessRestricted access - publisher's policy
drac.iddocument10221042
dc.description.versionPostprint (published version)
upcommons.citation.authorArdanuy, M.; Rodríguez-Pérez, M.; Saja, J. A. de; Velasco J.I.
upcommons.citation.publishedtrue
upcommons.citation.publicationNamePolymers for advanced technologies
upcommons.citation.volume23
upcommons.citation.number5
upcommons.citation.startingPage841
upcommons.citation.endingPage849


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