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dc.contributor.authorCarchi, Tany
dc.contributor.authorLapo, Byron
dc.contributor.authorAlvarado, José
dc.contributor.authorEspinoza Montero, Patricio J.
dc.contributor.authorLlorca Piqué, Jordi
dc.contributor.authorFernández, Lenys
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.date.accessioned2019-04-02T16:11:52Z
dc.date.available2019-04-02T16:11:52Z
dc.date.issued2019-02-06
dc.identifier.citationCarchi, T. [et al.]. A nafion film cover to enhance the analytical performance of the CuO/Cu electrochemical sensor for determination of chemical oxygen demand. "Sensors", 6 Febrer 2019, vol. 19, núm. 3, p. 1-17.
dc.identifier.issn1424-8220
dc.identifier.urihttp://hdl.handle.net/2117/131140
dc.description.abstractWe modified and evaluated the performance of a CuO/Cu electrochemical electrode for chemical oxygen demand (COD) determination by covering it with a Nafion (Nf) film. The resulting modified CuONf/Cu electrode sensor was used for the electrochemical determination of COD in river, slaughterhouse and estuarine water samples in order to evaluate its performance for this particular task. It was compared with the CuO/Cu sensor with no Nafion. The main electrochemical characteristics of interest, resistance, sensitivity, accuracy and reproducibility, were assessed by means of Linear Sweep Voltammetry using glucose as a standard. Results of these essays indicate that the procedure used produced smooth and firmly attached Nf films covering the whole copper surface. This sensor was shown to be resistant to interferences and effective in electro-oxidation of a wide range of organic compounds and therefore very useful for COD determination. Using the newly developed CuONf/Cu electrode an analytical linear range of 50 to 1000 mg·L-1 COD, with a detection limit of 2.11 mg·L-1 (n = 6) COD was achieved. The comparison shows that the CuONf/Cu sensor is more appropriate for COD determination than its counterpart with no Nafion.
dc.format.extent17 p.
dc.language.isoeng
dc.publisherMultidisciplinary Digital Publishing Institute (MDPI)
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Spain
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subjectÀrees temàtiques de la UPC::Enginyeria química
dc.subject.lcshSewage -- Purification
dc.subject.otherchemical oxygen demand
dc.subject.othercopper oxide electrode
dc.subject.othernafion film
dc.subject.otherdetection
dc.titleA nafion film cover to enhance the analytical performance of the CuO/Cu electrochemical sensor for determination of chemical oxygen demand
dc.typeArticle
dc.subject.lemacAigües residuals -- Depuració
dc.contributor.groupUniversitat Politècnica de Catalunya. NEMEN - Nanoenginyeria de materials aplicats a l'energia
dc.identifier.doi10.3390/s19030669
dc.description.peerreviewedPeer Reviewed
dc.relation.publisherversionhttps://www.mdpi.com/1424-8220/19/3/669
dc.rights.accessOpen Access
drac.iddocument23935551
dc.description.versionPostprint (published version)
upcommons.citation.authorCarchi, T.; Lapo, B.; Alvarado, J.; Espinoza, P.; Llorca, J.; Fernández, L.
upcommons.citation.publishedtrue
upcommons.citation.publicationNameSensors
upcommons.citation.volume19
upcommons.citation.number3
upcommons.citation.startingPage1
upcommons.citation.endingPage17


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