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Functional supramolecular tetrathiafulvalene-based films with mixed valences states
dc.contributor.author | Riba Moliner, Marta |
dc.contributor.author | Gómez Rodríguez, Andrés |
dc.contributor.author | Amabilino, David B. |
dc.contributor.author | Puigmartí Luis, Josep |
dc.contributor.author | González Campo, Arántzazu |
dc.contributor.other | Universitat Politècnica de Catalunya. Departament de Ciència dels Materials i Enginyeria Metal·lúrgica |
dc.date.accessioned | 2019-02-19T12:48:42Z |
dc.date.available | 2019-02-19T12:48:42Z |
dc.date.issued | 2016 |
dc.identifier.citation | Riba-Moliner, M. [et al.]. Functional supramolecular tetrathiafulvalene-based films with mixed valences states. "Polymer", 2016, vol. 103, p. 251-260. |
dc.identifier.issn | 0032-3861 |
dc.identifier.uri | http://hdl.handle.net/2117/129381 |
dc.description.abstract | Tetrathiafulvalene molecules substituted with a carboxylic acid group (TTFCOOH) were bound as redox-active moieties into a poly(4-vinyl pyridine) (P4VP) skeleton through non-covalent interactions (hydrogen bonds). The aspect of the resulting P4VP-TTFCOOH films showed a uniform and smooth morphology. Moreover, the redox function of TTFCOOH in P4VP-TTFCOOH was demonstrated using tetrachloroauric acid, iron(III) perchlorate and iodine vapors as doping agents. The oxidized states of TTFCOOH as well as the mixed valance state TTFCOOH0-TTFCOOH+• were generated in a controlled manner in solid state, resulting in an organic film capable of charge transport. The charge transport along the organic donor molecules hydrogen bonded to the polymer matrix was demonstrated employing Electrostatic Force Microscopy (EFM) |
dc.format.extent | 10 p. |
dc.language.iso | eng |
dc.publisher | Elsevier |
dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Spain |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
dc.subject | Àrees temàtiques de la UPC::Enginyeria química::Química orgànica |
dc.subject.lcsh | Hydrogen bonding |
dc.subject.lcsh | Polymers |
dc.subject.lcsh | Microscopy |
dc.subject.other | Polymer |
dc.subject.other | Tetrathiafulvalene (TTF) |
dc.subject.other | Thin film |
dc.subject.other | Poly(4-vinyl pyridine) (P4VP) |
dc.subject.other | Mixed valence state |
dc.subject.other | Hybrid polymer |
dc.subject.other | Electrostatic Force Microscopy (EFM) |
dc.subject.other | Charge transport |
dc.subject.other | Hydrogen bonding |
dc.title | Functional supramolecular tetrathiafulvalene-based films with mixed valences states |
dc.type | Article |
dc.subject.lemac | Enllaç hidrogen |
dc.subject.lemac | Polímers |
dc.subject.lemac | Microscòpia |
dc.identifier.doi | 10.1016/j.polymer.2016.09.039 |
dc.relation.publisherversion | https://www.sciencedirect.com/science/article/pii/S0032386116308382 |
dc.rights.access | Open Access |
local.identifier.drac | 23932969 |
dc.description.version | Postprint (author's final draft) |
local.citation.author | Riba-Moliner, M.; Gómez, A.G; Amabilino, D.B.; Puigmartí-Luis, J.; González-Campo, A. |
local.citation.publicationName | Polymer |
local.citation.volume | 103 |
local.citation.startingPage | 251 |
local.citation.endingPage | 260 |
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