Show simple item record

dc.contributor.authorPeres, Rafael S.
dc.contributor.authorFerreira, Carlos A.
dc.contributor.authorAlemán Llansó, Carlos
dc.contributor.authorArmelín Diggroc, Elaine Aparecida
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.identifier.citationPeres, R.S., Ferreira, C.A., Aleman, C., Armelin, E. Development of novel biobased epoxy films with aliphatic and aromatic amine hardeners for the partial replacement of Bisphenol A in primer coatings. A: "Biobased and environmentally benign coatings". Scrivener Publishing LLC, 2016, p. 121-148.
dc.description.abstractNew insights into epoxidized linseed oil (ELO) reaction with several amine hardeners for partial replacement of diglycidyl ether of bisphenol A (DGEBA) in coatings formulations are discussed. Thermosets formed by ELO and a variety of hardeners have been examined using 1H and 13C nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and scanning electron microscope (SEM) techniques. In addition, the mechanical properties, wettability, and swelling of the resulting films have been evaluated. Good properties of ELO cured with diamines, as hexamethylene diamine and p-phenylenediamine, were obtained. Both thermosets offer good impermeability to water, which is higher than that of the commercial epoxy resin, fabricated using DGEBA and polyaminoamide, and an excellent thermal stability. The mechanical behavior is also better than the brittle and rigid films obtained from DGEBA-based resins, films exhibiting the elastic-like behavior of rubber materials. This chapter offers new and promising perspectives in the use of vegetable oils for coatings formulations.
dc.format.extent28 p.
dc.publisherScrivener Publishing LLC
dc.subjectÀrees temàtiques de la UPC::Enginyeria química
dc.subject.lcshVegetable oils
dc.subject.lcshEpoxy resins
dc.subject.otherThermosetting plastics
dc.subject.othervegetable oils
dc.subject.otherepoxy resin
dc.subject.otheramine hardener
dc.titleDevelopment of novel biobased epoxy films with aliphatic and aromatic amine hardeners for the partial replacement of Bisphenol A in primer coatings
dc.typePart of book or chapter of book
dc.subject.lemacOlis vegetals
dc.subject.lemacResines epoxídiques
dc.contributor.groupUniversitat Politècnica de Catalunya. IMEM-BRT- Innovation in Materials and Molecular Engineering - Biomaterials for Regenerative Therapies
dc.description.peerreviewedPeer Reviewed
dc.rights.accessRestricted access - publisher's policy
dc.description.versionPostprint (published version)
local.citation.authorPeres, R.S.; Ferreira, C.A.; Aleman, C.; Armelin, E.
local.citation.publicationNameBiobased and environmentally benign coatings

Files in this item


This item appears in the following Collection(s)

Show simple item record

All rights reserved. This work is protected by the corresponding intellectual and industrial property rights. Without prejudice to any existing legal exemptions, reproduction, distribution, public communication or transformation of this work are prohibited without permission of the copyright holder