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Isomannide-containing poly(butylene 2,5-furandicarboxylate) copolyesters via ring opening polymerization
dc.contributor.author | Morales Huerta, Juan Carlos |
dc.contributor.author | Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon |
dc.contributor.author | León Cavanillas, Salvador |
dc.contributor.author | Muñoz Guerra, Sebastián |
dc.contributor.other | Universitat Politècnica de Catalunya. Departament d'Enginyeria Química |
dc.date.accessioned | 2018-06-27T07:34:13Z |
dc.date.available | 2019-04-02T00:30:57Z |
dc.date.issued | 2018-05-08 |
dc.identifier.citation | Morales, J., Martinez de Ilarduya, A., León, S., Muñoz, S. Isomannide-containing poly(butylene 2,5-furandicarboxylate) copolyesters via ring opening polymerization. "Macromolecules", 8 Maig 2018, vol. 51, núm. 9, p. 3340-3350. |
dc.identifier.issn | 0024-9297 |
dc.identifier.uri | http://hdl.handle.net/2117/118550 |
dc.description.abstract | Cyclic oligomers of isomannide 2,5-furandicarboxylate were synthesized using the high dilution condensation method. A mixture of dimer, trimer, and tetramer species largely enriched in dimer was obtained. These cyclic oligomers were made to react with oligo(butylene 2,5-furandicarboxylate) in bulk at 220 °C by ring opening polymerization using Sn(Oct)2 as a catalyst. A series of random poly(butylene 2,5-furandicarboxylate) copolyesters containing isomannide in a range of 5–50 mol % and with weight-average molecular weights between 30,000 and 50,000 g·mol–1 were prepared. These copolyesters started to decompose above 300 °C, and only those containing less than 10 mol % of isomannide showed signs of crystallinity. They displayed glass-transition temperatures in the 40–100 °C range with values increasing steadily with the content in isomannide. At difference with poly(butylene 2,5-furandicarboxylate) homopolyester that is reluctant to undergo hydrolysis, the isomannide-containing copolyesters were noticeably degraded by water, much more rapidly when exposed to lipases. |
dc.format.extent | 11 p. |
dc.language.iso | eng |
dc.publisher | American Chemical Society (ACS) |
dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Spain |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
dc.subject | Àrees temàtiques de la UPC::Enginyeria química |
dc.subject.lcsh | Oligomers |
dc.subject.lcsh | Ring-opening polymerization |
dc.subject.lcsh | Copolymers |
dc.subject.lcsh | Polyesters |
dc.subject.other | Ring Opening Polymerization |
dc.subject.other | cyclic oligomers |
dc.subject.other | Isomanide |
dc.subject.other | FDCA |
dc.subject.other | copolyesters |
dc.subject.other | renewable resources. |
dc.title | Isomannide-containing poly(butylene 2,5-furandicarboxylate) copolyesters via ring opening polymerization |
dc.type | Article |
dc.subject.lemac | Oligòmers |
dc.subject.lemac | Copolímers |
dc.subject.lemac | Polièsters |
dc.subject.lemac | Polimerització |
dc.contributor.group | Universitat Politècnica de Catalunya. POL - Polímers Industrials Avançats i Biopolímers Tecnològics |
dc.identifier.doi | 10.1021/acs.macromol.8b00487 |
dc.description.peerreviewed | Peer Reviewed |
dc.relation.publisherversion | https://pubs.acs.org/doi/10.1021/acs.macromol.8b00487 |
dc.rights.access | Open Access |
local.identifier.drac | 22520152 |
dc.description.version | Postprint (author's final draft) |
dc.relation.projectid | info:eu-repo/grantAgreement/MINECO/1PE/MAT2016-77345-C3-1-P |
dc.relation.projectid | info:eu-repo/grantAgreement/MINECO/1PE/MAT2012-38044-C03-03 |
local.citation.author | Morales, J.; Martinez de Ilarduya, A.; León, S.; Muñoz, S. |
local.citation.publicationName | Macromolecules |
local.citation.volume | 51 |
local.citation.number | 9 |
local.citation.startingPage | 3340 |
local.citation.endingPage | 3350 |
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