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dc.contributor.authorLópez Pérez, David Orencio
dc.contributor.authorSalud Puig, Josep
dc.contributor.authorRosario De la Fuente, M.
dc.contributor.authorSebastian Ugarteche, Nerea
dc.contributor.authorDíez Berart, Sergio
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament de Física
dc.date.accessioned2018-05-08T11:23:17Z
dc.date.issued2018-01-17
dc.identifier.citationLopez, D., Salud, J., Rosario, M., Sebastian, N., Diez, S. Cooperative behavior of molecular motions giving rise to two glass transitions in the same supercooled mesophase of a smectogenic liquid crystal dimer. "Physical review E", 17 Gener 2018, vol. 97, núm. 1, p. 012804-1-012804-8.
dc.identifier.issn2470-0045
dc.identifier.urihttp://hdl.handle.net/2117/117014
dc.description.abstractIn the present work, a detailed analysis of the glassy behavior and the relaxation dynamics of the liquid crystal dimer a-(4-cyanobiphenyl-4'-yloxy)-¿-(1-pyrenimine-benzylidene-4'-oxy) heptane (CBO7O.Py) throughout both nematic and smectic-A mesophases by means of broadband dielectric spectroscopy has been performed. CBO7O.Py shows three different dielectric relaxation modes and two glass transition (Tg) temperatures: The higher Tg is due to the freezing of the molecular motions responsible for the relaxation mode with the lowest frequency (µ1L); the lower Tg is due to the motions responsible for the two relaxation modes with highest frequencies (µ1H and µ2), which converge just at their corresponding Tg. It is shown how the three modes follow a critical-like description via the dynamic scaling model. The two modes with lowest frequencies (µ1L and µ1H) are cooperative in the whole range of the mesophases, whereas the highest frequency mode (µ2) is cooperative just below some crossover temperature. In terms of fragility, at the glass transition, the ensemble (µ1H+µ2) presents a value of the steepness index and µ1L a different one, meaning that fragility is a property intrinsic to the molecular motion itself. Finally, the steepness index seems to have a universal behavior with temperature for the dielectric relaxation modes of liquid crystal dimers, being almost constant at high temperatures and increasing drastically when cooling the compound down to the glass transition from a temperature about 34TNI.
dc.language.isoeng
dc.publisherAmerican Chemical Society (ACS)
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Spain
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subjectÀrees temàtiques de la UPC::Física
dc.subjectÀrees temàtiques de la UPC::Física::Física de l'estat sòlid
dc.subject.lcshLiquid crystals
dc.titleCooperative behavior of molecular motions giving rise to two glass transitions in the same supercooled mesophase of a smectogenic liquid crystal dimer
dc.typeArticle
dc.subject.lemacCristalls líquids
dc.contributor.groupUniversitat Politècnica de Catalunya. GRPFM - Grup de Recerca en Propietats Físiques dels Materials
dc.identifier.doi10.1103/PhysRevE.97.012704
dc.relation.publisherversionhttps://journals.aps.org/pre/abstract/10.1103/PhysRevE.97.012704
dc.rights.accessRestricted access - publisher's policy
drac.iddocument21889041
dc.description.versionPostprint (author's final draft)
dc.date.lift10000-01-01
upcommons.citation.authorLopez, D., Salud, J., Rosario, M., Sebastian, N., Diez, S.
upcommons.citation.publishedtrue
upcommons.citation.publicationNamePhysical review E
upcommons.citation.volume97
upcommons.citation.number1
upcommons.citation.startingPage012804-1
upcommons.citation.endingPage012804-8


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