Mostra el registre d'ítem simple
An efficient and reusable catalyst based on Pd/CeO2 for the room temperature aerobic Suzuki–Miyaura reaction in water/ethanol
dc.contributor.author | Amoroso, Francesco |
dc.contributor.author | Colussi, Sara |
dc.contributor.author | Del Zotto, Alessandro |
dc.contributor.author | Llorca Piqué, Jordi |
dc.contributor.author | Trovarelli, Alessandro |
dc.contributor.other | Universitat Politècnica de Catalunya. Institut de Tècniques Energètiques |
dc.date.accessioned | 2011-02-28T15:41:51Z |
dc.date.available | 2011-02-28T15:41:51Z |
dc.date.created | 2010 |
dc.date.issued | 2010 |
dc.identifier.citation | Amoroso, F. [et al.]. An efficient and reusable catalyst based on Pd/CeO2 for the room temperature aerobic Suzuki–Miyaura reaction in water/ethanol. "Journal of molecular catalysis A. Chemical", 2010, vol. 315, núm. 2, p. 197-204. |
dc.identifier.issn | 1381-1169 |
dc.identifier.uri | http://hdl.handle.net/2117/11584 |
dc.description.abstract | The Pd/CeO2 system behaves as an efficient precatalyst for the Suzuki–Miyaura cross-coupling under mild conditions (298 K, in air) in ethanol/water. A broad range of aryl bromides, including those deactivated, and arylboronic acids underwent Suzuki–Miyaura coupling with quantitative GC yields of asymmetric biaryls. Isolated yields and purity of the coupling products were good to excellent. A careful investigation through a series of suitable tests unequivocally showed that the C–C cross-coupling is accomplished via homogeneous mechanism by leached palladium(0). Noticeably, the Pd/CeO2 system can be recycled at least ten times without loss of activity. |
dc.format.extent | 8 p. |
dc.language.iso | eng |
dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Spain |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
dc.subject | Àrees temàtiques de la UPC::Enginyeria química::Química física |
dc.subject.lcsh | Catalysts |
dc.subject.lcsh | Ethanol |
dc.title | An efficient and reusable catalyst based on Pd/CeO2 for the room temperature aerobic Suzuki–Miyaura reaction in water/ethanol |
dc.type | Article |
dc.subject.lemac | Catalitzadors |
dc.contributor.group | Universitat Politècnica de Catalunya. GREENER - Grup de recerca d'estudis energètics i de les radiacions |
dc.identifier.doi | 10.1016/j.molcata.2009.09.012 |
dc.rights.access | Restricted access - publisher's policy |
local.identifier.drac | 5251770 |
dc.description.version | Postprint (published version) |
local.citation.author | Amoroso, F.; Colussi, S.; Del Zotto, A.; Llorca, J.; Trovarelli, A. |
local.citation.publicationName | Journal of molecular catalysis A. Chemical |
local.citation.volume | 315 |
local.citation.number | 2 |
local.citation.startingPage | 197 |
local.citation.endingPage | 204 |
Fitxers d'aquest items
Aquest ítem apareix a les col·leccions següents
-
Articles de revista [178]
-
Articles de revista [285]