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dc.contributor.authorBin Raja-Nazri, Raja Nazrul Hakim
dc.contributor.authorCailloux, Jonathan
dc.contributor.authorSantana Pérez, Orlando Onofre
dc.contributor.authorBou Serra, Jordi
dc.contributor.authorSánchez Soto, Miguel
dc.contributor.authorOdent, Jeremy
dc.contributor.authorRaquez, Jean-Marie
dc.contributor.authorDubois, Philippe
dc.contributor.authorCarrasco Alonso, Félix Ángel
dc.contributor.authorMaspoch Rulduà, Mª Lluïsa
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament de Ciència dels Materials i Enginyeria Metal·lúrgica
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.date.accessioned2017-06-16T14:11:53Z
dc.date.available2018-06-14T00:30:35Z
dc.date.issued2017-06-14
dc.identifier.citationBin, R., Cailloux, J., Santana, O., Bou, J. J., Sanchez-Soto, M., Odent, J., Raquez, J., Dubois, P., Carrasco, F., Maspoch, M. PLA/SiO2 composites: influence of the filler modifications on the morphology, crystallization behaviour and mechanical properties. "Journal of applied polymer science", 14 Juny 2017, vol. 134, p. 45367-45379.
dc.identifier.issn1097-4628
dc.identifier.urihttp://hdl.handle.net/2117/105549
dc.description.abstractFilms of an architecturally modified poly(lactic acid) (PLAREx) with three different types of fumed silica nanofillers (SiO2) were processed through reactive extrusion-calendering in a pilot plant. The effects of the SiO2 type on both the dispersion and the crystallization behaviour under dynamic and isothermal conditions are investigated using transmission electron microscopy (TEM) and differential scanning calorimetry (DSC). The mechanical properties are assessed by tensile testing. TEM micrographs showed that the improved chemical affinity of both surface-treated SiO2 towards PLAREx end groups did not improve particle dispersion. DSC results revealed that untreated SiO2 nucleated PLAREx more efficiently than both surface-modified silicas. The activation energy for the isothermal crystallization process, as determined by an Arrhenius method, suggests that addition of untreated SiO2 enhances the crystallization rate of PLAREx. However, it seems that the tensile behaviour remained unchanged whether silicas were added or not.
dc.format.extent13 p.
dc.language.isoeng
dc.publisherWiley
dc.subjectÀrees temàtiques de la UPC::Enginyeria química
dc.subject.lcshPolylactic acid
dc.subject.lcshNanocomposites (Materials)
dc.subject.lcshCrystallization
dc.subject.otherPoly(lactic acid)
dc.subject.otherReactive extrusion
dc.subject.otherNanocomposites
dc.subject.otherFumed silica
dc.subject.otherCrystallization behaviour
dc.titlePLA/SiO2 composites: influence of the filler modifications on the morphology, crystallization behaviour and mechanical properties
dc.typeArticle
dc.subject.lemacNanocompostos (Materials)
dc.subject.lemacÀcid polilàctic
dc.contributor.groupUniversitat Politècnica de Catalunya. POLY2 - Polyfunctional polymeric materials
dc.contributor.groupUniversitat Politècnica de Catalunya. Càtedra A3 ENGIBIO - Càtedra A3 d’Innovació en Cuir, Moda i Tèxtils
dc.description.peerreviewedPeer Reviewed
dc.rights.accessOpen Access
drac.iddocument21094684
dc.description.versionPostprint (author's final draft)
upcommons.citation.authorBin, R., Cailloux, J., Santana, O., Bou, J. J., Sanchez-Soto, M., Odent, J., Raquez, J., Dubois, P., Carrasco, F., Maspoch, M.
upcommons.citation.publishedtrue
upcommons.citation.publicationNameJournal of applied polymer science
upcommons.citation.volume134
upcommons.citation.startingPage45367
upcommons.citation.endingPage45379


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