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dc.contributor.authorHosseini Asl, Seyed Mostafa
dc.contributor.authorMasomi, Mojtaba
dc.contributor.authorHosseini, Morteza
dc.contributor.authorJavadian, Hamedreza
dc.contributor.authorRuiz Planas, Montserrat
dc.contributor.authorSastre Requena, Ana María
dc.contributor.otherUniversitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.date.accessioned2017-05-17T06:55:10Z
dc.date.available2019-04-02T00:30:55Z
dc.date.issued2017-04-01
dc.identifier.citationHosseini Asl, S., Masomi, M., Hosseini, M., Javadian, H., Ruiz, M., Sastre, A. Synthesis of hydrous iron oxide/aluminum hydroxide composite loaded on coal fly ash as an effective mesoporous and low-cost sorbent for Cr(VI) sorption: Fuzzy logic modeling. "Process safety and environmental protection", 1 Abril 2017, vol. 107, p. 153-167.
dc.identifier.issn0957-5820
dc.identifier.urihttp://hdl.handle.net/2117/104528
dc.description.abstractThe aim of this research was to estimate the possibility of using synthesized hydrous iron oxide/aluminium hydroxide composite loaded on coal fly ash (FA3) as an efficient sorbent for Cr(VI) sorption from aqueous solution. In this regard, dissolution and precipitation processes were performed to rearrange and load the intrinsic iron and aluminum on the surface of fly ash. Different characterization techniques including XRD, XRF, FT-IR, SEM, LPS and BET surface area were applied to analyze the sorbent properties. Moreover, sorption kinetics were studied using Morris–Weber intra-particle diffusion, Lagergren pseudo-first-order and pseudo-second-order models. The kinetic analyses indicated that pseudo-first-order model controlled the sorption process. In order to estimate the sorbent capacity, Langmuir, Freundlich and D–R models were applied. The thermodynamic parameters of Cr(VI) sorption were also studied. In addition, removal efficiency of Cr(VI) was predicted using the developed fuzzy logic model. The fuzzification of four input variables including pH, contact time, adsorbent dose and initial Cr(VI) concentration versus removal efficiency as output was carried out using an artificial intelligence-based approach. A Mamdani-type fuzzy interface system was employed to fulfill a collection of 24 rules (If-Then format) using triangle membership functions (MFS) with seven levels in fuzzy sets. The proposed fuzzy logic model demonstrated high predictive performance with correlation coefficient (R2) of 0.95 and acceptable deviation from the experimental data, confirming its suitability to predict Cr(VI) removal efficiency. Based on experimental data and statistical analysis, the synthetized sorbent was effective for treating wastewater containing Cr(VI).
dc.format.extent15 p.
dc.language.isoeng
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Spain
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subjectÀrees temàtiques de la UPC::Enginyeria química
dc.subject.lcshSewage--Purification
dc.subject.lcshFly ash
dc.subject.otherFly ash
dc.subject.otherFeOOH/Al(OH)3
dc.subject.otherSorption
dc.subject.otherCr(VI)
dc.subject.otherIsotherm
dc.subject.otherFuzzy logic modeling
dc.titleSynthesis of hydrous iron oxide/aluminum hydroxide composite loaded on coal fly ash as an effective mesoporous and low-cost sorbent for Cr(VI) sorption: Fuzzy logic modeling
dc.typeArticle
dc.subject.lemacAigües residuals -- Depuració
dc.subject.lemacCendres volants
dc.contributor.groupUniversitat Politècnica de Catalunya. SETRI - Grup de Tècniques de Separació i Tractament de Residus Industrials
dc.identifier.doi10.1016/j.psep.2017.02.012
dc.description.peerreviewedPeer Reviewed
dc.relation.publisherversionhttp://www.psep.ichemejournals.com/article/S0957-5820(17)30054-X/abstract
dc.rights.accessOpen Access
local.identifier.drac19771219
dc.description.versionPostprint (published version)
local.citation.authorHosseini Asl, S.; Masomi, M.; Hosseini, M.; Javadian, H.; Ruiz, M.; Sastre, A.
local.citation.publicationNameProcess safety and environmental protection
local.citation.volume107
local.citation.startingPage153
local.citation.endingPage167


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