Solid-State Colloidal CuInS2 Quantum Dot Solar Bulk Heterojunctions
PublisherRoyal Society of Chemistry
Rights accessOpen Access
European Commisision's projectENERGY - The Energy Story (EC-FP7-316616)
Colloidal copper indium sulfide (CIS) nanocrystals (NCs) are Pb- and Cd-free alternatives for use as absorbers in quantum dot solar cells. In a heterojunction with TiO2, non-annealed ligand-exchanged CIS NCs form solar cells yielding a meager power conversion efficiency (PCE) of 0.15%, with photocurrents plummeting far below predicted values from absorption. Decreasing the amount of zinc during post-treatment leads to improved mobility but marginally improves device performance (PCE = 0.30%). By incorporating CIS into a porous TiO2 network, we saw an overall drastic improvement in device performance, reaching PCEs of 1.16%, mainly from an increase in short circuit current density (Jsc) and fill factor (FF) and a 10-fold increase in internal quantum efficiency (IQE). We have determined that by moving from a bilayer to a bulk heterojunction architecture, we have reduced the trap-assisted recombination as seen in changes in the ideality factor, the intensity dependence of the photocurrent and transient photocurrent (TPC) and photovoltage (TPV) characteristics.
CitationSo, David; Pradhan, Santanu; Konstantatos, Gerasimos. "Solid-State Colloidal CuInS2 Quantum Dot Solar Bulk Heterojunctions". Royal Society of Chemistry, 2016.