Articles de revistahttp://hdl.handle.net/2117/57442018-12-15T16:46:29Z2018-12-15T16:46:29ZInfluence of extrinsic contribution on the macroscopic properties of hard and soft lead zirconate titanate ceramicsOchoa Guerrero, Diego A.García García, José EduardoPérez Pérez, RafaelAlbareda Tiana, Alfonsohttp://hdl.handle.net/2117/1212062018-09-18T01:55:55Z2018-09-17T08:18:05ZInfluence of extrinsic contribution on the macroscopic properties of hard and soft lead zirconate titanate ceramics
Ochoa Guerrero, Diego A.; García García, José Eduardo; Pérez Pérez, Rafael; Albareda Tiana, Alfonso
In this work, the contribution of the extrinsic effect to the macroscopic properties in soft and hard lead zirconate titanate ceramics is directly evaluated. Close to the room temperature, poled hard ceramics show an anomalous behavior, which is notably different from that of soft ceramics, not only in dielectric but also in piezoelectric and elastic responses. Hence, at room temperature their properties are thermally stable and the losses are unusually low. It is suggested that two mechanisms are present, with one mechanism inhibiting the other.
2018-09-17T08:18:05ZOchoa Guerrero, Diego A.García García, José EduardoPérez Pérez, RafaelAlbareda Tiana, AlfonsoIn this work, the contribution of the extrinsic effect to the macroscopic properties in soft and hard lead zirconate titanate ceramics is directly evaluated. Close to the room temperature, poled hard ceramics show an anomalous behavior, which is notably different from that of soft ceramics, not only in dielectric but also in piezoelectric and elastic responses. Hence, at room temperature their properties are thermally stable and the losses are unusually low. It is suggested that two mechanisms are present, with one mechanism inhibiting the other.Nonlinear behavior in a piezoelectric resonator: a method of analysisGarcía García, José EduardoPérez Pérez, RafaelAlbareda Tiana, AlfonsoMinguella Blasco, Enrichttp://hdl.handle.net/2117/1212002018-09-18T01:55:19Z2018-09-17T07:53:44ZNonlinear behavior in a piezoelectric resonator: a method of analysis
García García, José Eduardo; Pérez Pérez, Rafael; Albareda Tiana, Alfonso; Minguella Blasco, Enric
Theories used for understanding nonlinear behavior of piezoelectric resonators are usually only valid for a given range of amplitudes. Thus, important discrepancies can sometimes be observed between theory and experiment. In this work, a simplified model of the resonator is assumed in order to extend the analysis of nonlinear behavior to any kind of nonlinear function, without a significant increase of mathematical complexity. Nevertheless, nonlinearities are considered to be weak enough to be taken as perturbations. An asymptotic method is used to obtain the first and second order perturbations of the response to an harmonic excitation applied to the system, and each one is separated into Fourier series. Nonlinearity is described by two functions-/spl Phi/, (S,D,S/spl dot/,D/spl dot/) and /spl Psi/ (S,D,S/spl dot/,D/spl dot/)-that must be added to the constitutive equations that give T and E as functions of S and D. These functions can be split into their symmetrical and antisymmetrical parts, which have different incidence over the perturbation terms. In order to simplify the problem, no mechanical excitation is considered, the electrical one is taken as strictly harmonic, and the current rather than the e.m.f. is taken as initial data. As an application example, this method is applied in order to find the second harmonic generation for a particular kind of nonlinearity.
2018-09-17T07:53:44ZGarcía García, José EduardoPérez Pérez, RafaelAlbareda Tiana, AlfonsoMinguella Blasco, EnricTheories used for understanding nonlinear behavior of piezoelectric resonators are usually only valid for a given range of amplitudes. Thus, important discrepancies can sometimes be observed between theory and experiment. In this work, a simplified model of the resonator is assumed in order to extend the analysis of nonlinear behavior to any kind of nonlinear function, without a significant increase of mathematical complexity. Nevertheless, nonlinearities are considered to be weak enough to be taken as perturbations. An asymptotic method is used to obtain the first and second order perturbations of the response to an harmonic excitation applied to the system, and each one is separated into Fourier series. Nonlinearity is described by two functions-/spl Phi/, (S,D,S/spl dot/,D/spl dot/) and /spl Psi/ (S,D,S/spl dot/,D/spl dot/)-that must be added to the constitutive equations that give T and E as functions of S and D. These functions can be split into their symmetrical and antisymmetrical parts, which have different incidence over the perturbation terms. In order to simplify the problem, no mechanical excitation is considered, the electrical one is taken as strictly harmonic, and the current rather than the e.m.f. is taken as initial data. As an application example, this method is applied in order to find the second harmonic generation for a particular kind of nonlinearity.Unexpected dielectric response in lead zirconate titanate ceramics: The role of ferroelectric domain wall pinning effectsGarcía García, José EduardoGomis Arbonès, VicentePérez Pérez, RafaelAlbareda Tiana, AlfonsoEiras, Jose A.http://hdl.handle.net/2117/1211992018-09-18T01:55:53Z2018-09-17T07:41:15ZUnexpected dielectric response in lead zirconate titanate ceramics: The role of ferroelectric domain wall pinning effects
García García, José Eduardo; Gomis Arbonès, Vicente; Pérez Pérez, Rafael; Albareda Tiana, Alfonso; Eiras, Jose A.
Temperature dependent dielectric response has been measured in Pb(Zr1-xTix)O-3 ceramics. Samples of different compositions (x=0.40, 0.47, and 0.60), pure and doped with Nb-or Fe, were studied at temperatures between 15 and 700 K and in the frequency range from 100 Hz to 1 MHz. Unexpected dielectric behavior has been found around room temperature. Anomalous temperature dependent permittivity is observed in pure and Fe-doped samples but not in Nb-doped samples. The anomaly appears related to the presence of oxygen vacancies but not on the sample crystallographic phase. The authors suggest that the anomaly may be a manifestation of the domain wall pinning effect. (C) 2007 American Institute of Physics.
2018-09-17T07:41:15ZGarcía García, José EduardoGomis Arbonès, VicentePérez Pérez, RafaelAlbareda Tiana, AlfonsoEiras, Jose A.Temperature dependent dielectric response has been measured in Pb(Zr1-xTix)O-3 ceramics. Samples of different compositions (x=0.40, 0.47, and 0.60), pure and doped with Nb-or Fe, were studied at temperatures between 15 and 700 K and in the frequency range from 100 Hz to 1 MHz. Unexpected dielectric behavior has been found around room temperature. Anomalous temperature dependent permittivity is observed in pure and Fe-doped samples but not in Nb-doped samples. The anomaly appears related to the presence of oxygen vacancies but not on the sample crystallographic phase. The authors suggest that the anomaly may be a manifestation of the domain wall pinning effect. (C) 2007 American Institute of Physics.Optimization of elastic nonlinear behavior measurements of ceramic piezoelectric resonators with burst excitationAlbareda Tiana, AlfonsoPérez Pérez, RafaelCasals Mirones, JorgeGarcía García, José EduardoOchoa Guerrero, Diego A.http://hdl.handle.net/2117/1211332018-09-15T01:55:43Z2018-09-14T09:08:02ZOptimization of elastic nonlinear behavior measurements of ceramic piezoelectric resonators with burst excitation
Albareda Tiana, Alfonso; Pérez Pérez, Rafael; Casals Mirones, Jorge; García García, José Eduardo; Ochoa Guerrero, Diego A.
A system of nonlinear measurement and nonlinear elastic characterization of resonators is presented, which increases the possibilities and characteristics of the other classic nonlinear characterization methods. This characterization has been necessary due to the use of resonators in power devices, where their behavior departs from the linear characteristics. The use of burst signals and a system of acquisition and data processing is proposed instead of impedance analyzers, thus avoiding the thermal effects associated with the high-signal measures, which are necessary for this characterization. The measures are repeated for different amplitudes and at the same frequency near the resonance by a single amplitude sweep, which is simpler and faster to carry out than the multiple frequency sweepings used in other methods. As a last resort, a variation on the proposed method, closer to the classical measures, is put forward, in which the resonance is ensured in all the measures. Special emphasis is placed on obtaining nonlinear characterization of the piezoceramic material in order to increase its optimization in the transducers in terms of both its use and its composition and structure.
2018-09-14T09:08:02ZAlbareda Tiana, AlfonsoPérez Pérez, RafaelCasals Mirones, JorgeGarcía García, José EduardoOchoa Guerrero, Diego A.A system of nonlinear measurement and nonlinear elastic characterization of resonators is presented, which increases the possibilities and characteristics of the other classic nonlinear characterization methods. This characterization has been necessary due to the use of resonators in power devices, where their behavior departs from the linear characteristics. The use of burst signals and a system of acquisition and data processing is proposed instead of impedance analyzers, thus avoiding the thermal effects associated with the high-signal measures, which are necessary for this characterization. The measures are repeated for different amplitudes and at the same frequency near the resonance by a single amplitude sweep, which is simpler and faster to carry out than the multiple frequency sweepings used in other methods. As a last resort, a variation on the proposed method, closer to the classical measures, is put forward, in which the resonance is ensured in all the measures. Special emphasis is placed on obtaining nonlinear characterization of the piezoceramic material in order to increase its optimization in the transducers in terms of both its use and its composition and structure.Light-induced capacitance tunability in ferroelectric crystalsPáez Margarit, DavidRubio Marcos, FernandoOchoa Guerrero, Diego A.Del Campo Garcia, Angel AdolfoFernández Lozano, José FranciscoGarcía García, José Eduardohttp://hdl.handle.net/2117/1204502018-08-03T00:55:26Z2018-08-02T08:04:16ZLight-induced capacitance tunability in ferroelectric crystals
Páez Margarit, David; Rubio Marcos, Fernando; Ochoa Guerrero, Diego A.; Del Campo Garcia, Angel Adolfo; Fernández Lozano, José Francisco; García García, José Eduardo
The remote controlling of ferroic properties with light is nowadays a hot and highly appealing topic in materials science. Here, we shed light on some of the unresolved issues surrounding light–matter coupling in ferroelectrics. Our findings show that the capacitance and, consequently, its related intrinsic material property, i.e., the dielectric constant, can be reversibly adjusted through the light power control. High photodielectric performance is exhibited across a wide range of the visible light wavelength because of the wavelength-independence of the phenomenon. We have verified that this counterintuitive behavior can be strongly ascribed to the existence of “locally free charges” at domain wall.
2018-08-02T08:04:16ZPáez Margarit, DavidRubio Marcos, FernandoOchoa Guerrero, Diego A.Del Campo Garcia, Angel AdolfoFernández Lozano, José FranciscoGarcía García, José EduardoThe remote controlling of ferroic properties with light is nowadays a hot and highly appealing topic in materials science. Here, we shed light on some of the unresolved issues surrounding light–matter coupling in ferroelectrics. Our findings show that the capacitance and, consequently, its related intrinsic material property, i.e., the dielectric constant, can be reversibly adjusted through the light power control. High photodielectric performance is exhibited across a wide range of the visible light wavelength because of the wavelength-independence of the phenomenon. We have verified that this counterintuitive behavior can be strongly ascribed to the existence of “locally free charges” at domain wall.Enhancement of piezoelectric properties stability of submicron-structured piezoceramics obtained by spark plasma sinteringOchoa Guerrero, Diego A.Suñol Galofre, Francesc XavierRubio Marcos, FernandoGarcía García, José Eduardohttp://hdl.handle.net/2117/1196822018-07-21T00:59:46Z2018-07-20T12:48:32ZEnhancement of piezoelectric properties stability of submicron-structured piezoceramics obtained by spark plasma sintering
Ochoa Guerrero, Diego A.; Suñol Galofre, Francesc Xavier; Rubio Marcos, Fernando; García García, José Eduardo
Grain-size effect on functional properties of piezoceramics is nowadays an important topic due to the potential applications of these materials at the submicron scale. In this context, we explore the effect of the grain size reduction on the functional properties stability of piezoceramics. Submicron- and micro-structured Pb(Zr,Ti)O3-based materials are taken as model samples to carry out this study. Rayleigh analysis is used to quantitatively evaluate the domain wall contribution. The results show that the stability of properties depends strongly on grain size. Specifically, the nonlinear response decreases significantly when the grain size is reduced to the submicron scale. This behavior can be explained by taking into account that a grain size reduction involves a grain boundary increment, which may clamp domain walls. The results suggest that grain size engineering may be an effective alternative to the widely used compositional engineering in order to control the undesirable nonlinear behavior in piezoceramics.
2018-07-20T12:48:32ZOchoa Guerrero, Diego A.Suñol Galofre, Francesc XavierRubio Marcos, FernandoGarcía García, José EduardoGrain-size effect on functional properties of piezoceramics is nowadays an important topic due to the potential applications of these materials at the submicron scale. In this context, we explore the effect of the grain size reduction on the functional properties stability of piezoceramics. Submicron- and micro-structured Pb(Zr,Ti)O3-based materials are taken as model samples to carry out this study. Rayleigh analysis is used to quantitatively evaluate the domain wall contribution. The results show that the stability of properties depends strongly on grain size. Specifically, the nonlinear response decreases significantly when the grain size is reduced to the submicron scale. This behavior can be explained by taking into account that a grain size reduction involves a grain boundary increment, which may clamp domain walls. The results suggest that grain size engineering may be an effective alternative to the widely used compositional engineering in order to control the undesirable nonlinear behavior in piezoceramics.Low Weber number jet collision regimes in microgravitySuñol Galofre, Francesc XavierGonzález Cinca, Ricardohttp://hdl.handle.net/2117/1137632018-11-01T01:30:23Z2018-02-05T15:59:14ZLow Weber number jet collision regimes in microgravity
Suñol Galofre, Francesc Xavier; González Cinca, Ricardo
The outcome of the collision between two liquid jets depends on the liquid properties, jet velocity, and impact angle. So far studies on liquid jet impingement have been carried out in normal gravity conditions. In microgravity, jets are not accelerated and can show a different behavior than on ground. We perform an experimental analysis of the injection of liquid jets in microgravity, focusing in the jet impingement at different velocities and impact angles at low Weber numbers. Several regimes are obtained, some of which are not observable on ground. Other regimes take place at different parameter ranges than in normal gravity. A map of the observed regimes is proposed in terms of the Weber number and the impact angle.
2018-02-05T15:59:14ZSuñol Galofre, Francesc XavierGonzález Cinca, RicardoThe outcome of the collision between two liquid jets depends on the liquid properties, jet velocity, and impact angle. So far studies on liquid jet impingement have been carried out in normal gravity conditions. In microgravity, jets are not accelerated and can show a different behavior than on ground. We perform an experimental analysis of the injection of liquid jets in microgravity, focusing in the jet impingement at different velocities and impact angles at low Weber numbers. Several regimes are obtained, some of which are not observable on ground. Other regimes take place at different parameter ranges than in normal gravity. A map of the observed regimes is proposed in terms of the Weber number and the impact angle.Relationship between the two-component system 1-Br-adamantane + 1-Cl-adamantane and the high-pressure properties of the pure componentsBarrio Casado, María delLevit Valenzuela, RafaelLloveras Muntané, Pol MarcelAznar Luque, AraceliNegrier, PhilippeMondieig, DeniseTamarit Mur, José Luishttp://hdl.handle.net/2117/1132282018-09-19T00:48:06Z2018-01-26T08:18:02ZRelationship between the two-component system 1-Br-adamantane + 1-Cl-adamantane and the high-pressure properties of the pure components
Barrio Casado, María del; Levit Valenzuela, Rafael; Lloveras Muntané, Pol Marcel; Aznar Luque, Araceli; Negrier, Philippe; Mondieig, Denise; Tamarit Mur, José Luis
The temperature-composition phase diagram of the two-component system 1-Br-adamantane and 1-Cl-adamantane has been determined by means of thermal analysis techniques and X-ray powder diffraction from the low-temperature phase to the liquid state.
The crossed isopolymorphism formalism has been applied to the two-component system to infer the normal pressure properties of the orthorhombic metastable phase of 1-Cl-adamantane at normal pressure. The experimental pressure-temperature phase diagrams for the involved compounds are related to the two-phase equilibria determined at normal pressure and inferences about the monotropic behavior of the aforementioned orthorhombic phase are discussed.
2018-01-26T08:18:02ZBarrio Casado, María delLevit Valenzuela, RafaelLloveras Muntané, Pol MarcelAznar Luque, AraceliNegrier, PhilippeMondieig, DeniseTamarit Mur, José LuisThe temperature-composition phase diagram of the two-component system 1-Br-adamantane and 1-Cl-adamantane has been determined by means of thermal analysis techniques and X-ray powder diffraction from the low-temperature phase to the liquid state.
The crossed isopolymorphism formalism has been applied to the two-component system to infer the normal pressure properties of the orthorhombic metastable phase of 1-Cl-adamantane at normal pressure. The experimental pressure-temperature phase diagrams for the involved compounds are related to the two-phase equilibria determined at normal pressure and inferences about the monotropic behavior of the aforementioned orthorhombic phase are discussed.Limit cycle bifurcations in resonant LC power inverters under zero current switching strategyBenadero García-Morato, LuisPonce, EnriqueEl Aroudi, AbdelaliTorres Peral, Franciscohttp://hdl.handle.net/2117/1113982018-02-05T15:58:29Z2017-11-30T18:10:12ZLimit cycle bifurcations in resonant LC power inverters under zero current switching strategy
Benadero García-Morato, Luis; Ponce, Enrique; El Aroudi, Abdelali; Torres Peral, Francisco
The dynamics of a DC-AC self-oscillating LC resonant inverter with a zero current switching strategy is considered in this paper. A model that includes both the series and the parallel topologies and accounts for parasitic resistances in the energy storage components is used. It is found that only two reduced parameters are needed to unfold the bifurcation set of this extended system: one is related to the quality factor of the LC resonant tank, and the other accounts for the balance between serial and parallel losses. Through a rigorous mathematical study, a complete description of the bifurcation set is obtained and the parameter regions where the inverter can work properly is emphasized.
2017-11-30T18:10:12ZBenadero García-Morato, LuisPonce, EnriqueEl Aroudi, AbdelaliTorres Peral, FranciscoThe dynamics of a DC-AC self-oscillating LC resonant inverter with a zero current switching strategy is considered in this paper. A model that includes both the series and the parallel topologies and accounts for parasitic resistances in the energy storage components is used. It is found that only two reduced parameters are needed to unfold the bifurcation set of this extended system: one is related to the quality factor of the LC resonant tank, and the other accounts for the balance between serial and parallel losses. Through a rigorous mathematical study, a complete description of the bifurcation set is obtained and the parameter regions where the inverter can work properly is emphasized.Insight into the dynamics of low temperature dielectric relaxation of ordinary perovskite ferroelectricsLevit Valenzuela, RafaelOchoa Guerrero, Diego A.Martínez García, Julio CesarGarcía García, José Eduardohttp://hdl.handle.net/2117/1113962017-12-01T03:26:26Z2017-11-30T17:44:21ZInsight into the dynamics of low temperature dielectric relaxation of ordinary perovskite ferroelectrics
Levit Valenzuela, Rafael; Ochoa Guerrero, Diego A.; Martínez García, Julio Cesar; García García, José Eduardo
The temperature dependence of the dielectric response of ordinary ferroelectric materials exhibits a frequency-independent anomalous peak as a manifestation of the ferroelectric to paraelectric phase transition. A second anomaly in the permittivity has been reported in different ferroelectric perovskite-type systems at low temperatures, often at cryogenic temperatures. This anomaly manifests as a frequency-dependent local maximum, which exhibits similar characteristics to that observed in relaxor ferroelectrics around their phase transition. The origin of this unexpected behavior is still controversial. In order to clarify this phenomenon, a model-free route solution is developed in this work. Our findings reveal the same critical linear pattern/glass-like freezing behavior previously observed for glass-forming systems. Contrary to current thought, our results suggest that a critical-like dynamic parameterization could provide a more appropriate solution than the conventional Vogel–Fulcher–Tammann equation. The implemented methodology may open a new pathway for analyzing relaxation phenomena in other functional materials like relaxor ferroics.
2017-11-30T17:44:21ZLevit Valenzuela, RafaelOchoa Guerrero, Diego A.Martínez García, Julio CesarGarcía García, José EduardoThe temperature dependence of the dielectric response of ordinary ferroelectric materials exhibits a frequency-independent anomalous peak as a manifestation of the ferroelectric to paraelectric phase transition. A second anomaly in the permittivity has been reported in different ferroelectric perovskite-type systems at low temperatures, often at cryogenic temperatures. This anomaly manifests as a frequency-dependent local maximum, which exhibits similar characteristics to that observed in relaxor ferroelectrics around their phase transition. The origin of this unexpected behavior is still controversial. In order to clarify this phenomenon, a model-free route solution is developed in this work. Our findings reveal the same critical linear pattern/glass-like freezing behavior previously observed for glass-forming systems. Contrary to current thought, our results suggest that a critical-like dynamic parameterization could provide a more appropriate solution than the conventional Vogel–Fulcher–Tammann equation. The implemented methodology may open a new pathway for analyzing relaxation phenomena in other functional materials like relaxor ferroics.