Now showing items 1-7 of 7

    • A facile approach to hydrophilic oxidized fullerenes and their derivatives as cytotoxic agents and supports for nanobiocatalytic systems 

      Zygouri, Panagiota; Spyrou, Konstantinos; Mitsari, Efstratia; Barrio Casado, María del; Macovez, Roberto; Patila, Michaela; Stamatis, Haralambo; Verginadis, Ioannis; Velalopoulou, Anastasia; Evangelou, Angelos; Sideratou, Zili; Gournis, Dimitrios; Rudolf, Petra (Nature, 2020-12-01)
      Article
      Open Access
      A facile, environment-friendly, versatile and reproducible approach to the successful oxidation of fullerenes (oxC60) and the formation of highly hydrophilic fullerene derivatives is introduced. This synthesis relies on ...
    • Hopping conductivity and polarization effects in a fullerene derivative salt 

      Macovez, Roberto; Zachariah, Manesh; Romanini, Michela; Zygouri, Panagiota; Gournis, Dimitrios; Tamarit Mur, José Luis (2014-06-12)
      Article
      Restricted access - publisher's policy
      Impedance spectroscopy is employed to probe the frequency-dependent conductivity and dielectric response of the C60O24Na 24 fulleride. The conduction properties of this organic material match the so-called universal behavior ...
    • Polymorphism with conformational isomerism and incomplete crystallization in solid ethanolamine 

      Romanini, Michela; Negrier, Philippe; Tripathi, Pragya; Gournis, Dimitrios; Lira, Kyriaki-Marina; Barrio Casado, María del; Pardo Soto, Luis Carlos; Tamarit Mur, José Luis; Macovez, Roberto (2019-09-25)
      Article
      Open Access
      We employ calorimetry, Rietveld refinement of X-ray powder diffraction, broadband dielectric spectroscopy and molecular dynamics simulations, to investigate the phase behavior, crystal structure, dc conductivity and ...
    • Ultraslow dynamics of water in organic molecular solids 

      Macovez, Roberto; Mitsari, Efstratia; Zachariah, Manesh; Romanini, Michela; Zygouri, Panagiota; Gournis, Dimitrios; Tamarit Mur, José Luis (2014-03-06)
      Article
      Restricted access - publisher's policy
      The relaxation dynamics of water in hygroscopic molecular solids is probed by broadband dielectric spectroscopy in the temperature range from 200 to 450 K. Evidence is found for three types of dynamic processes. The ...
    • Variable-range electron hopping, conductivity cross-over and space-charge relaxation in C60Br6 

      Manesh, Zachariah; Romanini, Michela; Zygouri, Panagiota; Gournis, Dimitrios; Tamarit Mur, José Luis; Barrio Casado, María del; Macovez, Roberto (2016-07-01)
      Article
      Open Access
      Dielectric spectroscopy is employed to probe the frequency-dependent conductivity and dipolar dielectric response of solid C60Br6. Below approximately 215 K, charge conduction is electronic and well described by Mott's ...
    • Water-triggered conduction and polarization effects in a hygroscopic fullerene salt 

      Zachariah, Manesh; Tripathi, Pragya; Mitsari, Efstratia; Romanini, Michela; Zygouri, Panagiota; Gournis, Dimitrios; Barrio Casado, María del; Tamarit Mur, José Luis; Macovez, Roberto (2014)
      Conference lecture
      Open Access
      Impedance spectroscopy is employed to probe the frequency-dependent conductivity and dielectric response of the crystalline C60O24Na24 fulleride, both in its pure form obtained by heating to 473 K and in its bulk-hydrate ...
    • Water-Triggered Conduction Mediated by Proton Exchange in a Hygroscopic Fulleride and Its Hydrate 

      Zachariah, Manesh; Mitsari, Efstratia; Romanini, Michela; Zygouri, Panagiota; Gournis, Dimitrios; Barrio Casado, María del; Tamarit Mur, José Luis; Macovez, Roberto (2015-01-08)
      Article
      Open Access
      Impedance spectroscopy is employed to probe the impact of water on the dc conductivity and ac dielectric response of the polycrystalline C-60(ONa)(24) fulleride, both in its bulk-hydrate form, stable only below 370 K, and ...