Tuning supramolecular aurophilic structures: the effect of counterion, positive charge and solvent
PublisherRoyal Society of Chemistry
Rights accessRestricted access - publisher's policy (embargoed until 2017-05-07)
The synthesis of the cationic gold(I) complexes [Au(CuCC5H4N)(CH3-PTA)] X (X = I, 1; X = OTf, 4), [Au(C equivalent to CC5H4N-CH3)(PTA)] X (X = I, 2; X = OTf = 5; PTA = 1,3,5-triaza-7-phosphatricyclo[220.127.116.11.7]decane) and [Au(CuCC5H4N-CH3)(DAPTA)] X (X = I, 3; X = OTf = 6, DAPTA = 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[ 3.3.1]nonane) results in cationic complexes with unexpected supramolecular assemblies in water ranging from rod-like structures (1) to vesicles (2 and 3) and square-like structures (5 and 6). These morphologies are completely different from the fibers previously obtained with their parent neutral complexes [Au(C equivalent to C5H4N)(PTA)] and [Au(C equivalent to C5H4N)(DAPTA)]. Nevertheless, the introduction of triflate as a counterion in 1 (complex 4) gives rise to the formation of a highly soluble complex in water which does not display any significant aggregation in solution. These results reveal the importance of the introduction of a positive charge on global supramolecular assemblies and how the counterion can also modify the resulting package. Interestingly, we have also proved that the aggregation of complexes 2, 3, 5 and 6 is also affected by the solvent with direct influence on their absorption and emission properties and the global morphology of the aggregates.
CitationAguilo, E., Gavara, R., Baucells, C., Guitart, M., Lima, J.C., Llorca, J., Rodríguez, L. Tuning supramolecular aurophilic structures: the effect of counterion, positive charge and solvent. "Dalton transactions", 01 Gener 2016, vol. 45, núm. 17, p. 7328-7339.
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