Pd2Au36(SR)(24) cluster: structure studies
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The location of the Pd atoms in Pd2Au36(SC2H4Ph)(24), is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd-S bonds, which is supported by far infrared spectroscopy and by comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.
CitationZhang, B., Kaziz, S., Llorca, J. Pd2Au36(SR)(24) cluster: structure studies. "Nanoscale", 01 Gener 2015, vol. 7, núm. 40, p. 17012-17019.
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