Recent Submissions

  • Bio-based PBS copolyesters derived from a bicyclic D-glucitol 

    Zakharova, Elena; Alla Bedahnane, Abdelilah; Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon; Muñoz Guerra, Sebastián (2015-05-12)
    Article
    Restricted access - publisher's policy
    2,4:3,5-di-O-methylene-D-glucitol (Glux-diol) was used for the synthesis of poly(butylene succinate) (PBS) copolyesters by melt polycondensation. Glux-diol possess a rigid bicyclic asymmetric structure made of two fused ...
  • Dielectric relaxations in poly(glycidyl phenyl ether): Effects of microstructure and cyclic topology 

    Gambino, Thomas; Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon; Alegría, Angel; Barroso Burjans, Fabienne (American Chemical Society (ACS), 2016-02-09)
    Article
    Restricted access - publisher's policy
    Cyclic and linear, isoregic and aregic, and isotactic and atactic poly(glycidyl phenyl ether) (PGPE) with molecular weights up to Mw = 5.5 kg/mol are synthesized by ring-opening polymerization of glycidyl phenyl ether. ...
  • Poly(alkylene 2,5-furandicarboxylate)s (PEF and PBF) by ring opening polymerization 

    Morales Huerta, Juan Carlos; Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon; Muñoz Guerra, Sebastián (Elsevier, 2016-03-22)
    Article
    Restricted access - publisher's policy
    The preparation of cyclic ethylene and butylene 2,5-furandicarboxylate oligoesters and their conversion to furan-based polyesters poly(ethylene furanoate) (PEF) and poly(butylene furanoate) (PBF) by ring-opening polymerization ...
  • Cationic poly(butylene succinate) copolyesters 

    Bautista, Mayka; Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon; Alla, Abdelilah; Vives, Marc; Morató Farreras, Jordi; Muñoz Guerra, Sebastián (2016-02-01)
    Article
    Restricted access - publisher's policy
    The synthesis, characterization and comparative evaluation of properties of two series of cationic PBS copolyesters bearing respectively ammonium and tributylphosphonium side groups, are reported. The copolyesters with ...
  • Poly(butylene succinate) ionomers with enhanced hydrodegradability 

    Bautista, Mayka; Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon; Alla Bedahnane, Abdelilah; Muñoz Guerra, Sebastián (2015-07-09)
    Article
    Open Access
    A series of poly(butylene succinate) (PBS) ionomers containing up to 14 mol%of sulfonated succinate units have been synthesized by polycondensation in the melt-phase. The copolyesters were obtained with weight average ...
  • Copolyesters made from 1,4-butanediol, sebacic acid, and D-glucose by melt and enzymatic polycondensation 

    Japu, Cristina; Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon; Alla Bedahnane, Abdelilah; Jiang, Yi; Loos, Katja; Muñoz Guerra, Sebastián (2015-03-09)
    Article
    Open Access
    Biotechnologically accessible 1,4-butanediol and vegetal oil-based diethyl sebacate were copolymerized with bicyclic acetalized d-glucose derivatives (Glux) by polycondensation both in the melt at high temperature and in ...
  • Configurational entropy calculation of poly(alpha-alkyl beta,L-aspartate)s amorphous and crystalline films using gas permeation 

    del Castillo, L. F.; Andrio Balado, Andreu; Nava, J.A.; Molla, S.; Muñoz Guerra, Sebastián; Compañ Morreno, Vicente (2014-10-01)
    Article
    Restricted access - publisher's policy
    The permeability and diffusion coefficient of gases such as N-2, O-2 and CO2 through two polymeric membranes of poly(alpha-alkyl beta,L-aspartate)s (PAALA-n) were determined by the
  • Chemical structure and microstructure of poly(alkylene terephthalate)s, their copolyesters, and their blends as studied by NMR 

    Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon; Muñoz Guerra, Sebastián (2014-11-17)
    Article
    Restricted access - publisher's policy
    The use of NMR spectroscopy in solution to investigate the chemical structure of engineering poly(alkylene terephthalate)s such as poly(ethylene terephthalate) (PET), poly(trimethylene terephthalate) (PTT), and poly(butylene ...
  • Modification of properties of poly(butylene succinate) by copolymerization with tartaric acid-based monomers 

    Zakharova, Elena; Lavilla, Cristina; Alla Bedahnane, Abdelilah; Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon; Muñoz Guerra, Sebastián (2014-12-01)
    Article
    Restricted access - publisher's policy
    The two cyclic acetals, 2,3-di-O-methylene-l-threitol and dimethyl 2,3-di-O-methylene-l-threarate, were used for the synthesis of two series of PBS copolyesters differing in which unit, butylene or succinate, was replaced, ...
  • Biodegradable copolyesters of poly(hexamethylene terephthalate) containing bicyclic 2,4:3,5-di-O-methylene-D-glucarate units 

    Japu, Cristina; Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon; Alla Bedahnane, Abdelilah; García Martín, Maria de Gracia; Galbis Pérez, Juan Antonio; Muñoz Guerra, Sebastián (2014-11-01)
    Article
    Restricted access - publisher's policy
    A set of copolyesters (PHTxGluxy) with compositions ranging between 90/10 and 50/50 in addition to the parent homopolyesters poly(hexamethylene terephthalate) (PHT) and PHGlux, are prepared by the melt polycondensation of ...

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