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dc.contributor.authorAmoroso, Francesco
dc.contributor.authorColussi, Sara
dc.contributor.authorDel Zotto, Alessandro
dc.contributor.authorLlorca Piqué, Jordi
dc.contributor.authorTrovarelli, Alessandro
dc.contributor.otherUniversitat Politècnica de Catalunya. Institut de Tècniques Energètiques
dc.date.accessioned2011-03-14T08:52:32Z
dc.date.available2011-03-14T08:52:32Z
dc.date.created2011-02-12
dc.date.issued2011-02-12
dc.identifier.citationAmoroso, F. [et al.]. PdO hydrate as an efficient and recyclable catalyst for the Suzuki-Miyaura reaction in water/ethanol at room temperature. "Catalysis communications", 12 Febrer 2011, vol. 12, núm. 6, p. 563-567.
dc.identifier.issn1566-7367
dc.identifier.urihttp://hdl.handle.net/2117/11795
dc.description.abstractPdO·1.4H2O 1 prepared in our laboratories, as well as commercially available palladium oxides 2–4 have been found to act as efficient catalysts for the Suzuki–Miyaura reaction in ethanol/water mixture at room temperature in air. Thus, in the presence of 1 mol% catalyst, the reaction between different aryl bromides and arylboronic acids afforded a wide range of functionalized biphenyls in quantitative yield. Catalyst 1 has shown to be the most active for all couples of substrates, and it can be recovered and recycled several times without marked loss of activity. It has been demonstrated by means of suitable tests that the true catalyst is a soluble form of palladium originated by metal leaching from the metal oxide precursor. It is worth of note that the amount of catalyst both in the solution and in the isolated organic product is about 1 ppm.
dc.format.extent5 p.
dc.language.isoeng
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Spain
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subjectÀrees temàtiques de la UPC::Enginyeria química::Química física
dc.subject.lcshCatalysis
dc.subject.lcshChemistry, Physical and theoretical
dc.titlePdO hydrate as an efficient and recyclable catalyst for the Suzuki-Miyaura reaction in water/ethanol at room temperature
dc.typeArticle
dc.subject.lemacFisicoquímica
dc.subject.lemacCatàlisi
dc.contributor.groupUniversitat Politècnica de Catalunya. GREENER - Grup de recerca d'estudis energètics i de les radiacions
dc.identifier.doi10.1016/j.catcom.2010.11.026
dc.rights.accessRestricted access - publisher's policy
local.identifier.drac5352715
dc.description.versionPostprint (published version)
local.citation.authorAmoroso, F.; Colussi, S.; Del Zotto, A.; Llorca, J.; Trovarelli, A.
local.citation.publicationNameCatalysis communications
local.citation.volume12
local.citation.number6
local.citation.startingPage563
local.citation.endingPage567


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