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A green strategy for the synthesis of poly(ethylene succinate) and its copolyesters via enzymatic ring opening polymerization
| dc.contributor.author | Morales Huerta, Juan Carlos |
| dc.contributor.author | Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon |
| dc.contributor.author | Muñoz Guerra, Sebastián |
| dc.contributor.other | Universitat Politècnica de Catalunya. Departament d'Enginyeria Química |
| dc.date.accessioned | 2017-09-20T05:04:19Z |
| dc.date.available | 2019-10-24T00:25:21Z |
| dc.date.issued | 2017-10 |
| dc.identifier.citation | Morales, J., Martinez de Ilarduya, A., Muñoz, S. A green strategy for the synthesis of poly(ethylene succinate) and its copolyesters via enzymatic ring opening polymerization. "European polymer journal", Octubre 2017, vol. 95, p. 514-519. |
| dc.identifier.issn | 0014-3057 |
| dc.identifier.uri | http://hdl.handle.net/2117/107793 |
| dc.description.abstract | Poly(ethylene succinate) (PES) with weight-average molecular weight above 60,000 g mol-1 was efficiently obtained by enzymatic ring opening polymerization of cyclic oligo(ethylene succinate)s c(ES)n, which in turn were prepared by lipase-catalysed cyclocondensation in solution of dimethyl succinate and ethylene glycol. The methodology was demonstrated to be also applicable to the synthesis of high molecular weight PES-copolyesters containing butylene succinate, e-hydroxycaproate or L-lactate units with a random distribution. |
| dc.format.extent | 6 p. |
| dc.language.iso | eng |
| dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Spain |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
| dc.subject | Àrees temàtiques de la UPC::Enginyeria química |
| dc.subject.lcsh | Polymerization |
| dc.subject.lcsh | Polyesters |
| dc.subject.lcsh | Polymers |
| dc.subject.other | Cyclic oligoesters |
| dc.subject.other | Enzymatic synthesis |
| dc.subject.other | Poly(ethylene succinate) |
| dc.subject.other | ROP |
| dc.title | A green strategy for the synthesis of poly(ethylene succinate) and its copolyesters via enzymatic ring opening polymerization |
| dc.type | Article |
| dc.subject.lemac | Polimerització |
| dc.subject.lemac | Polímers |
| dc.subject.lemac | Polièsters |
| dc.contributor.group | Universitat Politècnica de Catalunya. POL - Polímers Industrials Avançats i Biopolímers Tecnològics |
| dc.identifier.doi | 10.1016/j.eurpolymj.2017.08.043 |
| dc.description.peerreviewed | Peer Reviewed |
| dc.relation.publisherversion | http://www.sciencedirect.com/science/article/pii/S0014305717313083?via%3Dihub |
| dc.rights.access | Open Access |
| local.identifier.drac | 21478682 |
| dc.description.version | Postprint (author's final draft) |
| local.citation.author | Morales, J.; Martinez de Ilarduya, A.; Muñoz, S. |
| local.citation.publicationName | European polymer journal |
| local.citation.volume | 95 |
| local.citation.startingPage | 514 |
| local.citation.endingPage | 519 |
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